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Chemical categorization solvents

Absorption processes are categorized based on the mechanism of absorption, as either chemical or physical. In addition, a number of hybrid absorption processes featuring both chemical and physical solvents have been developed. [Pg.210]

The phenomena enumerated in Section 2.4 do not, of course, fully describe all the differences between chemical and electrode processes of ion radical formation. From time to time, effects are found that cannot be clearly interpreted and categorized. For instance, one paper should be mentioned. It bears the symbolic title ir- and a-Diazo Radical Cations Electronic and Molecular Structure of a Chemical Chameleon (Bally et al. 1999). In this work, diphenyldiazomethane and its 15N2, 13C, and Di0 isotopomers, as well as the CH2-CH2 bridged derivative, 5-diazo-10,ll-dihydro-5H-dibenzo[a,d]cycloheptene, were ionized via one-electron electrolytic or chemical oxidation. Both reactions were performed in the same solvent (dichloromethane). Tetra-n-butylammonium tetrafluoroborate served as the supporting salt in the electrolysis. The chemical oxidation was carried out with tris(4-bromophenyl)-or tris(2,4-dibromophenyl)ammoniumyl hexachloroantimonates. Two distinct cation radicals that corresponded to it- and a-types were observed in both types of one-electron oxidation. These electromers are depicted in Scheme 2-28 for the case of diphenyldiazomethane. [Pg.119]

Answer The term lipid does not specify a particular chemical structure. Whereas one can write a general formula for an amino acid, nucleic acid, or protein, lipids are much more chemically diverse. Compounds are categorized as lipids based on their greater solubility in organic solvents than in water. [Pg.99]

Other enthalpic interactions depend on the chemical nature of the species being solvated. For example, solvents that can act as electron-pair donors (Lewis bases) can undergo specific interactions with metal cations that are electron-pair acceptors (Lewis acids). Notably, the transition metals may act as Lewis acids due to their unfilled d-orbitals the specific nature of the interaction depends on the particular coordination characteristics of the metal ion. Lewis acid-base interactions are categorized as specific chemical. [Pg.117]


See other pages where Chemical categorization solvents is mentioned: [Pg.2695]    [Pg.87]    [Pg.491]    [Pg.9]    [Pg.387]    [Pg.138]    [Pg.115]    [Pg.491]    [Pg.415]    [Pg.543]    [Pg.271]    [Pg.311]    [Pg.234]    [Pg.210]    [Pg.97]    [Pg.1497]    [Pg.5]    [Pg.5]    [Pg.122]    [Pg.175]    [Pg.13]    [Pg.871]    [Pg.42]    [Pg.56]    [Pg.203]    [Pg.127]    [Pg.154]    [Pg.204]    [Pg.189]    [Pg.611]    [Pg.524]    [Pg.481]    [Pg.285]    [Pg.247]    [Pg.694]    [Pg.44]    [Pg.188]    [Pg.7]    [Pg.18]    [Pg.614]    [Pg.271]    [Pg.290]    [Pg.9]    [Pg.286]    [Pg.135]   
See also in sourсe #XX -- [ Pg.5 ]




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Chemical categorization

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