Cathodoluminescence method

T. Miyata, K. Tsubokawa, and M. Kitamura, Observation of synthetic emeralds by scanning cathodoluminescence method,/. Gemmol Soc., Japan, 18,1993, 3-14... 

FIGURE 3 Composition dependence of the direct energy gap Eg, measured by the cathodoluminescence method, of AlxGai.xN alloys over the entire range of 0 < x < 1 (after [16]). 

The temperature dependence of the diffusion coefficients of Al, Ga and In was studied. The cleavage cross-sectional surface of a diffused ZnSe wafer was observed by the SEM cathodoluminescence method. The following relations were obtained ... 

Band gaps in semiconductors can be investigated by other optical methods, such as photoluminescence, cathodoluminescence, photoluminescence excitation spectroscopy, absorption, spectral ellipsometry, photocurrent spectroscopy, and resonant Raman spectroscopy. Photoluminescence and cathodoluminescence involve an emission process and hence can be used to evaluate only features near the fundamental band gap. The other methods are related to the absorption process or its derivative (resonant Raman scattering). Most of these methods require cryogenic temperatures. 

It is worth summarizing at this point the different excitation methods used for phosphors that will be referred to throughout this chapter. There are three types photoluminescence (PL) which is based on initial excitation by absorption of light, cathodoluminescence (CL) which is based on bombardment with a beam of electrons, as in a cathode ray tube (CRT) and electroluminescence (EL) which is based on application of an electric field (either a.c. or d.c.) across the phosphor. 

Figure 6.2. Cathodoluminescence tomograph of an emerald crystal synthesized by the high-temperature solution growth method. Note the regularly spaced faint growth banding appearing in between two distinct bands. (By courtesy of T. Miyata.)...

Wurtz-synthesized PMPS was selected as the material to be studied when subjected to cathodoluminescence (CL).98 The CL method of the study of PMPS is based on the measurement of CL intensity of emitted light after its passage through the specimen, as shown in Figure 20. For the PMPS degradation measurements, electron beam energy of 10k eV was used. The PL emission spectrum consists of two emission bands. The maximum of the... 

During this century there has been considerable interest in the application of thermoluminescence studies to the recent history of meteorites. Natural TL provides a means of exploring radiation history and thermal environment in a manner which is complementary to isotopic methods, and the measurement of natural TL is now routine for the numerous meteorites being returned each year from the Antarctic (3,4). However, induced TL measurements have also proved of considerable interest, because the measurements have implications for the earliest history of meteorites. Essentially, the induced TL properties of meteorites are determined, with a few notable exceptions, by the amount and the nature of the feldspar in them, and feldspar is very sensitive to the major processes experienced by meteorites. In the present paper, we describe our recent work on the induced TL properties of meteorites and briefly discuss how these data relate to early meteorite history. We emphasize the relationship between the TL data and mineral properties. We also present here detailed descriptions of the cathodoluminescence properties of primitive meteorites, as these provide new insights into mineralogical controls on TL properties. 

Note A/B implies A grown or strained to B and vice versa. A B implies no growth direction or explicit strain dependence, i.e. natural. ) T = theoretical E = experimental AVL = average lattice XPS = X-ray photoelectron spectroscopy PL = photoluminescence CL = cathodoluminescence UPS = ultraviolet photoelectron spectroscopy LMTO = linear muffin tin orbital method LAPW = linearised augmented plane wave method PWP = plane wave pseudopotential method VCA = virtual crystal approximation. 

Kominami, H., Nakamura, T., Sowa, K., Nakanishi, Y, Hatanaka, Y, and Shi-maoka, G., Low voltage cathodoluminescent properties of phosphors coated with lUjOj by sol-gel method, App/. Surf. ScL, 113-114, 519, 1997. 

Depending on the excitation method used, luminescence techniques are divided into photoluminescence excited by photons, cathodoluminescence generated under the action of cathode rays, X-ray luminescence excited by X-rays, candoluminescence generated under the action of heat, and sonoluminescence excited by ultrasound. Emission generated under the action of a stream of ions from alkali metals in vaccum is called ionoluminescence radiation which atoms emit on optical excitation in plasma is known as atomic fluorescence chemiluminescence is the emission of radiation generated by the energy of chemical reactions, it does not require an external excitation source. The excitation source needed in each particular case is chosen on the basis of this classification. 

Samples were impregnated with a high-temperature blue-dyed epoxy resin before thin-section preparation. Polished thin sections were examined with a petrographic microscope and by using a hot-cathodoluminescence (CL) microscope (Matter Ramseyer, 1985). Most of the samples were stained using Dickson s (1966) method, and point counted (300 points per sample). 

The amount and quality of information in these studies varies greatly and only a few of the more recent papers applied a combination of several different methods to decipher the origin of saddle dolomite. We scanned published work for the following information on saddle dolomite occurrences optical mineralogy, cathodoluminescence (CL) characteristics, elemental composition, carbon, oxygen and strontium isotopic compositions, and fluid inclusion analysis. In the following sections we shall address these types of data in detail. 

In this chapter common methods to evaluate chemical properties and phase composition of bioceramic coatings will be briefly described that are available in many laboratories including X-ray diffraction (XRD), vibrational spectroscopy techniques such as infrared (FTIR) and Raman spectroscopy and nuclear magnetic resonance spectroscopy (NMR). These methods provide a host of information on bulk phase composition, degree of crystallinity and crystallite size. Some special techniques including cathodoluminescence serve to reveal intrinsic coating properties that cannot be assessed by conventional analytical techniques, for example to distinguish between amorphous calcium phosphate (ACP) and crystalline calcium phosphates. 

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