Cathodic stripping voltammetry CSV

Cathodic stripping voltammetry (CSV) is the mirror image of ASV It involves anodic deposition of the analyte, followed by stripping in a negative-going potential scan ... 

While ASV is used to measure metal cations, cathodic stripping voltammetry (CSV) can be used to measure some anions. Mercury is known to dissolve as mercurous ion (Hgl+) at a potential more positive than 220 mV vs. SSC. The Hg + forms insoluble salts with many anions such as halides, S2-, CN , SCN-, SH, etc. 

Analytical Applications In addition to the above-mentioned analytical aspects of the processes at Hg electrodes, in this section, we briefly review the papers focused on the subject of the affinity of various compounds to the mercury electrode surface, which allowed one to elaborate stripping techniques for the analysis of inorganic ions. Complexes of some metal ions with surface-active ligands were adsorptively accumulated at the mercury surface. After accumulation, the ions were determined, usually applying cathodic stripping voltammetry (CSV). Representative examples of such an analytical approach are summarized as follows. 

Cathodic stripping voltammetry (CSV) involves anodic (oxidative) deposition of an insoluble film of material on the electrode it is subsequently stripped off during a negative-going potential sweep [9]. Most CSV applications rely on the anodic accumulation of sparingly soluble mercury compounds on a mercury surface ... 

Separations may also be made on the basis of complex stability In such cases, a complexant is added to the sample and metal complexes are fractionated by a particular technique and their concentration is monitored (Apte and Batley, 1995 Miller and Bruland, 1997), typically by fluorescence (Aster et al., 1997), ultraviolet-visible (UV-Vis) spectrophotometry (Senesi, 1992 Bjorklund and Morrison, 1997), atomic absorption following solvent extraction (Itabashi et al., 1997), cathodic stripping voltammetry (CSV) (van den Berg et al., 1990 Yokoi et al., 1995 Maxwell and Smyth, 1996 Achterberg et al., 1997) or anodic stripping voltammetry (ASV)... 

Humic substances (HS) were determined in water using catalytic cathodic stripping voltammetry (CSV).113 This method was based on the adsorptive properties of iron-HS complexes on the mercury drop electrode at natural pH. HS were also determined in water using a method based on the binding of a dye, Toluidine Blue (TB), to HS molecules to produce a dye-HS complex, which caused a decrease in absorbance at 630 nm.114 The method was rapid, sensitive, and practicable. 

Electrochemical techniques anodic stripping voltammetry (ASV) and cathodic stripping voltammetry (CSV) for determining trace elements, and potentiometric sensors for determining dissolved gases (C02, N02, S02, NH3, H2S, HCN, and HF) as well as chloride, fluoride, cyanide, and sulfide. 

Helmers, E., Mergel, N. Platinum and rhodium in a polluted environment smdying the emissions of automobile catalysts with emphasis on the application of cathodic-stripping voltammetry (CSV) rhodium analysis. Fresenius J. Anal. Chem. 362, 522-528 (1998)... 

Cathodic stripping voltammetry (CSV) may be considered the reverse of ASV in that the electrolytic deposition step is carried out at a positive (anodic) applied potential, the deposited analate then being stripped by application of a cathodic voltage scan. CSV has been used for the determination of various anions ... 

Voltammetry, anodic stripping voltammetry (ASV), cathodic stripping voltammetry (CSV)... 

Terminology related to electroanalytical chemistry are chronoamperometry, voltammetry, coulometry, amperometric titrimetry, coulometric titrimetry, conductivity, con-ductimetry and high frequency titrimetry, electrometric titrimetry, electrogravimetry, electrodeposition, anodic stripping voltammetry (ASV), cathodic stripping voltammetry (CSV), polarography, differentia] pulse polarography (DPP), ion-selective electrode (ISE), ion-specific electrode (ISE), molecular selective electrode, potentiometry, potentio-metric titrimetry, and chronopotentiometric titrimetry. 

Adenine and guanine can be analyzed at a carbon electrode and adenine and cytosine at a mercury electrode by differential pulse voltammetry (po-larography) (DPV, DPP) at micromolar concentrations. Determination of bases by cathodic stripping voltammetry (CSV) (see above) gives substantially better sensitivities. In addition to the nucleic acid... 

The enrichment in cathodic stripping voltammetry (CSV) occurs by formation of sparingly soluble compounds of the species to be determined with ions from the material of the electrode forming a film on the surface of the WE. The commonly used WE is the HMDE. The enrichment voltage Up ) is such that the material of the WE is oxidized in presence of the substance being analyzed. The more insoluble the compound formed, the more negative will be the voltage at which the oxidation of the electrode material will occur (Nemst equation). 

Arsenic, selenium, and tellurium can be determined at the trace level by cathodic stripping voltammetry (CSV) after having been reductively codeposited with copper. A characteristic of the stripping technique of these three elements is that only a single current peak which arises from the further reduction of the deposited analyte to As. Se" or Te " is observed. This method is suitable for the determination and speciation of As(V) and As(IlI) in water samples [36], selenium in minerals [38] and biological samples [68], and for the simultaneous determination of selenium and tellurium (Fig. 41) [37]. 

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