Catalytic converter Environmental Protection Agency

Amination of aromatic nitro compounds is a very important process in both industry and laboratory. A simple synthesis of 4-aminodiphenyl amine (4-ADPA) has been achieved by utilizing a nucleophilic aromatic substitution. 4-ADPA is a key intermediate in the rubber chemical family of antioxidants. By means of a nucleophibc attack of the anilide anion on a nitrobenzene, a o-complex is formed first, which is then converted into 4-nitrosodiphenylamine and 4-nitrodiphenylamine by intra- and intermolecular oxidation. Catalytic hydrogenation finally affords 4-ADPA. Azobenzene, which is formed as a by-product, can be hydrogenated to aniline and thus recycled into the process. Switching this new atom-economy route allows for a dramatic reduction of chemical waste (Scheme 9.9).73 The United States Environmental Protection Agency gave the Green Chemistry Award for this process in 1998.74... 

Environmental Protection Agency without any modifications or accessories.32 However, concerns over cancer from Diesel exhaust have made the issue quite complicated in recent years, but those concerns are only for long-term effects. In any event, Diesels have always produced far less than 1%/vol. carbon monoxide, which is still the CO standard for all internal combustion engines. Gasoline engines have only met the same standard after many years of intensive research and the addition of many engine modifications and complex accessories including catalytic converters. 

The 1970 Clean Air Act, introduced by the US Environmental Protection Agency, included regulations requiring the control of automobile emissions. Lead compounds used to increase the octane rating of gasoline were to be phased out from 1973. All new cars, starting with 1975 models, would be fitted with catalytic converters and use unleaded gasoline. 

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