Casson constant

Plastic fluids are Newtonian or pseudoplastic liquids that exhibit a yield value (Fig. 3a and b, curves C). At rest they behave like a solid due to their interparticle association. The external force has to overcome these attractive forces between the particles and disrupt the structure. Beyond this point, the material changes its behavior from that of a solid to that of a liquid. The viscosity can then either be a constant (ideal Bingham liquid) or a function of the shear rate. In the latter case, the viscosity can initially decrease and then become a constant (real Bingham liquid) or continuously decrease, as in the case of a pseudoplastic liquid (Casson liquid). Plastic flow is often observed in flocculated suspensions. 

The time constant tc is related to the rate of aggregation of particles due to Brownian motion. For highly concentrated dispersed systems, oc will be much lower than t]o, so that (i oo/i o)yield stress, and Equation (2.11) reduces to the Casson model (Equation 2.6) (Tiu et al., 1992) with the Casson yield... 

Casson high shear rate viscosity (Pa s) consistency of power law fluid (Pa - sn) constant (Pa - sn) length (m) constant... 

Casson models were used to compare their yield stress results to those calculated with the direct methods, the stress growth and impeller methods. Table 2 shows the parameters obtained when the experimental shear stress-shear rate data for the fermentation suspensions were fitted with all models at initial process. The correlation coefficients (/P) between the shear rate and shear stress are from 0.994 to 0.995 for the Herschel-Bulkley model, 0.988 to 0.994 for the Bingham, 0.982 to 0.990 for the Casson model, and 0.948 to 0.972 for the power law model for enzymatic hydrolysis at 10% solids concentration (Table 1). The rheological parameters for Solka Floe suspensions were employed to determine if there was any relationship between the shear rate constant, k, and the power law index flow, n. The relationship between the shear rate constant and the index flow for fermentation broth at concentrations ranging from 10 to 20% is shown on Table 2. The yield stress obtained by the FL 100/6W impeller technique decreased significantly as the fimetion of time and concentration during enzyme reaction and fermentation. 

The power law, Herschel-Bulkley equation, and Casson model are simple and easy to use. However, these equations only work for modeling steady shear flows rather than transient or elongational flows. Thus, many other models have been proposed to fit experimental data more closely for food materials. Among these, it is worth mentioning the Ree-Eyring equation which has three constants... 

In other terms, above a critical shear stress, it flows as a Newtonian fluid of (constant) viscosity t). It follows that a fluid obeying the Herschel-Bulkley model is sometimes called a generalized Bingham fluid, since with n=1 and K=r in Equation 5.3, one obviously obtains Equation 5.4. The three fit parameters of the Herschel-Bulkley equation can be reduced to two, when considering that n=0.5. This was in fact the approach used by Casson in proposing the following model ... 

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