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Carbonate acidizing function

H. Yanai, H. Ogura, H. Fukaya, A. Kotani, F. Kusu, T. Taguchi, An effective method to introduce carbon acid functionality 2,2-bis(trifluoro methanesulfonyl)ethylation reaction of arenes, Chem. Eur. J. 17 (2011) 11747-11751. [Pg.288]

Converting aldehydes and ketones to cyanohydrins is of synthetic value for two reasons (1) a new carbon-carbon bond is formed and (2) the cyano group in the prod uct can be converted to a carboxylic acid function (CO2H) by hydrolysis (to be discussed in Section 19 12) or to an amine of the type CH2NH2 by reduction (to be discussed m Section 22 9)... [Pg.720]

Ammo acids are classified as a p 7 and so on according to the location of the amine group on the carbon chain that contains the carboxylic acid function... [Pg.1110]

In the Strecker synthesis an aldehyde is converted to an a ammo acid with one more carbon atom by a two stage procedure m which an a ammo nitrile is an mterme diate The a ammo nitrile is formed by reaction of the aldehyde with ammonia or an ammonium salt and a source of cyanide ion Hydrolysis of the nitrile group to a car boxylic acid function completes the synthesis... [Pg.1121]

Oxidation and chlorination of the catalyst are then performed to ensure complete carbon removal, restore the catalyst chloride to its proper level, and maintain full platinum dispersion on the catalyst surface. Typically, the catalyst is oxidized in sufficient oxygen at about 510°C for a period of six hours or more. Sufficient chloride is added, usually as an organic chloride, to restore the chloride content and acid function of the catalyst and to provide redispersion of any platinum agglomeration that may have occurred. The catalyst is then reduced to return the metal components to their active form. This reduction is accompHshed by using a flow of electrolytic hydrogen or recycle gas from another Platforming unit at 400 to 480°C for a period of one to two hours. [Pg.224]

The hydroxamic acid function in most alicyclic and aromatic compounds is stable to hot dilute acid or alkali, and derivatives cannot undergo normal base-catalyzed Lessen rearrangement. Di Maio and Tardella," however, have shown that some alicyclic hydroxamic acids when treated with polyphosphoric acid (PPA) at 176°-195° undergo loss of CO, CO.2, or H2O, in a series of reactions which must involve earlj fission of the N—0 bond, presumably in a phosphoryl-ated intermediate. Thus, l-hydroxy-2- piperidone(108) gave carbon monoxide, 1-pyrroline (119), and the lactams (120 and 121). The saturated lactam is believed to be derived from disproportionation of the unsaturated lactam. [Pg.229]

The transformation of the hydrophobic periphery composed of bromo substituents into a hydrophilic wrapping of carboxylic acid functions was achieved by reacting 31 with (i) n-butyllithium and (ii) carbon dioxide. The polymer-analogous transformation provides water soluble, amphiphilic derivatives of 31 which constitute useful covalently bonded unimolecular models for micellar structures. [Pg.41]

Ammonia is usually classified as a neutralizing amine because it provides post-boiler section corrosion inhibition through the same carbonic acid neutralization mechanism as regular amines. Similarly, hydrazine and other VOSs that produce ammonia, may be classified as functional neutralizing amines. [Pg.521]

FIGURE 10 JO The fractional composition of the species in carbonic acid as a function of pH. Note that the more fully protonated species are dominant at lower pH. [Pg.552]

The transformation of the terminal bromo substituents to carboxylic acid functions with (i) n-butyl lithium (ii) carbon dioxide, provides water soluble derivatives of 47 which are interesting as models for unimolecular micelles. [Pg.188]

The addition of perfluoroalkyl iodides to simple olefins has been quite successful under aqueous conditions to synthesize fluorinated hydrocarbons.119 In addition to carbon-based radicals, other radicals such as sulfur-based radicals, generated from RSH-type precursors (R = alkyl, acyl) with AIBN, also smoothly add to a-allylglycines protected at none, one, or both of the amino acid functions (NH2 and/or CO2H). Optimal results were obtained when both the unsaturated amino... [Pg.67]


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See also in sourсe #XX -- [ Pg.24 ]

See also in sourсe #XX -- [ Pg.24 ]




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Acidic function

Acidic functionalities

Acidity functions

Carbon function

Carbon functionalization

Carbon functionalized

Carbon functionalizing

Carbon nanotubes functionalizing carboxylic acid functionalities

Carbonate functionality

Carbonate matrix acidizing function

Carbonic acid functional derivations

Carboxylic acids, functional derivatives Acid anhydrides, Amides, carbonic

Functional derivatives of carbonic acid

Functionalized carbon materials solid acids

Single-walled carbon nanotube carboxylic acid-functionalized SWNTs

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