Carbinol networks

We have shown that similar networks formed from bis(chloromethyl)biphenyl (BCMBP) exhibit surface areas as high as 1,904 m g [31]. Webster and coworkers have prepared HCPs by treating 4,4 -dilithiobiphenyl (as well as other multi-lithiated aromatic compounds) with dimethylcarbonate to generate polymeric carbinol networks with surface areas of 400-1,000 m g [24]. More recently, poly silane element-organic frameworks was synthesized via a lithiation route to yield microporous networks with BET surface areas in the range 780-1,046 m g" [40]. 

Both competing reductions consume the cofactor nicotinamide adenine dinucleotide (NADH) and thereby interfere with the redox balance of the cell and feedback on glycolysis where NADH is regenerated on the one hand, while on the other hand NAD+ is required to keep the glycolytic pathway running. The nonlinear dynamical model combines the network of glycolysis and the additional pathways of the xenobiotics to predict the asymmetric yield (enantiomeric excess, ee) of L-versus D-carbinol for different environmental conditions (Fig. 3.4). Here, the enantiomeric excess of fluxes vy and i>d is defined as... 

Only a few properties of rigid aromatic hydrocarbon networks were hitherto described in the literature. They mostly deal with solubility, porosity and surface area, and the relationship between certain polymerization procedures and the nature of the polymeric products. The hyperbranched poyphenylenes and triaryl carbinols are fully amorphous substances [380, 383, 384], When dry, they are... 

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