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Cage Effects on Stability and Molecular Dynamics of Amine Radicals in Zeolites

2 Cage Effects on Stability and Molecular Dynamics of Amine Radicals in Zeolites [Pg.293]

The ESR studies using amine radicals as a spin probe have been extended to investigate cage effects on stability and molecular dynamics of organic molecules in zeolites [62]. Three zeolites with different cages or channels were employed, i.e.. [Pg.293]

Strongly temperature dependent ESR spectra were observed for the [(CH3)3NCH2] radical cation stabilized in Al-offretite and SAPO-42, see [Pg.294]

Semiconductor-based heterogeneous photocatalysts have been interested by a large number of scientists. Titanium dioxide (T1O2), whieh is inexpensive, nontoxic, resistant to photo-corrosion, and has high oxidative power, is the most widely used [Pg.295]

The advantage of T102 as a semiconductor photocatalyst comes from its ability of converting photon energy into chemical energy. The absorption of photons [Pg.296]




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Amine Radical

Amine effect

Amine stabilizers

Cage effect

Cage effect dynamics

Cage, radical

Cages of zeolite

Caging effects

Dynamic "stabilization

Dynamical effects

Dynamics caging

Dynamics effect

Effect of amines

Molecular Radicals

Molecular stability and

Molecular stabilization

Molecular zeolite

Radical cage effect

Radical caged

Radical effective

Radical in Zeolite

Radicals effects

Radicals stability

Radicals zeolites

Stability , effects

Stability of radicals

Stabilization effects

Stabilization zeolites

Stabilized effects

Stabilizer 37 -molecular

Stabilizing effect

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