Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

C directed

Figure C2.16.2. The sequence of atoms in tlie two poly types of SiC, zincblende and wurtzite, along tlie c-direction. The zincblende lattice has perfect tetraliedral angles. Figure C2.16.2. The sequence of atoms in tlie two poly types of SiC, zincblende and wurtzite, along tlie c-direction. The zincblende lattice has perfect tetraliedral angles.
The c axis corresponds to both the short axis of the crystal and the axis along the molecular chain. The observed repeat distance in the c direction is what would be expected between successive substituents on a fully extended hydrocarbon chain with normal bond lengths and angles (see Sec. 1.2). [Pg.235]

Cobalt trifluoride is readily prepared by reaction of fluorine (qv) and C0CI2 at 250°C or C0F2 at 150—180°C. Direct fluorination of C0F2 leads to quantitative yields of 99.9% pure CoF (4). [Pg.178]

Fig. 5. Direct red dyes, (a) Direct Red 81 described ia text (68) (b) Direct Red 2 (o-toLidiae coupled to two moles of naphthionic acid) (69) (c) Direct Red 23 (aniline coupled to 6,6 -ureylenebis-l-naplitliol-3-sulfonic acid with a second coupling with j aminoacetanilide) (70) and Direct Red 80 (2 mol 6-amino-3,4 -azobenzenedisulfonic acid coupled twice to 6,6 -ureylenebis-l-naphthol-3-sulfonic acid) (73). Direct Red 24 (4-aniino-y -toluenesulfonic acid coupled under acidic conditions to 6,6 -ureylenebis-l-naphthol-3-sulfonic acid followed by an alkaline coupling of o-anisidine) (71) (d) Direct Red 72 (Broenner s acid, ie, 6-artiino-2-naphthalenesulfonic acid coupled under acidic conditions to 6,6 -ureylenebis-l-naphthol-3-sulfonic acid followed by an... Fig. 5. Direct red dyes, (a) Direct Red 81 described ia text (68) (b) Direct Red 2 (o-toLidiae coupled to two moles of naphthionic acid) (69) (c) Direct Red 23 (aniline coupled to 6,6 -ureylenebis-l-naplitliol-3-sulfonic acid with a second coupling with j aminoacetanilide) (70) and Direct Red 80 (2 mol 6-amino-3,4 -azobenzenedisulfonic acid coupled twice to 6,6 -ureylenebis-l-naphthol-3-sulfonic acid) (73). Direct Red 24 (4-aniino-y -toluenesulfonic acid coupled under acidic conditions to 6,6 -ureylenebis-l-naphthol-3-sulfonic acid followed by an alkaline coupling of o-anisidine) (71) (d) Direct Red 72 (Broenner s acid, ie, 6-artiino-2-naphthalenesulfonic acid coupled under acidic conditions to 6,6 -ureylenebis-l-naphthol-3-sulfonic acid followed by an...
Class C direct dyes are dyes of poor leveling power which exhaust well in the absence of salt and the only way of controlling the rate of exhaustion is by temperature control. These dyes have high neutral affinity where, resulting from the complexity of the molecules, the nonionic forces of attraction dominate. When dyeing with these dyes it is essential to start at a low temperature with no added electrolyte, and to bring the temperature up to the boil very slowly without any addition of electrolyte. Once at the bod the dyeing is continued for 45—60 min with portionwise addition of salt to complete exhaustion. [Pg.354]

Wei and Robbins [10] have reviewed much of the work performed on the thermal physical properties of CBCF. Fhe emissivity parallel to the fibers was 0.8 over the temperature range from 1000 to 1800 °C. This value is higher than the emissivity of c-direction pyrolytic graphite (0.5-0.6), but is close to values for graphite and dense carbon-carbon composite (0.8-0.95). [Pg.176]

Fig. 6. Radiation damage in graphite showing the induced crystal dimensional strains. Impinging fast neutrons displace carbon atoms from their equilibrium lattice positions, producing an interstitial and vacancy. The coalescence of vacancies causes contraction in the a-direction, whereas interstitials may coalesce to form dislocation loops (essentially new graphite planes) causing c-direction expansion. Fig. 6. Radiation damage in graphite showing the induced crystal dimensional strains. Impinging fast neutrons displace carbon atoms from their equilibrium lattice positions, producing an interstitial and vacancy. The coalescence of vacancies causes contraction in the a-direction, whereas interstitials may coalesce to form dislocation loops (essentially new graphite planes) causing c-direction expansion.
Table 10.18(c) Direct-indicating Drager diffusion tubes - no pump required... [Pg.353]

Schnell, R., Stamm, M. and Creton, C., Direct correlation between interfacial width and adhesion in glassy polymers. Macromolecules, 31, 2284-2292 (1998). [Pg.241]

Pure NI3 has not been isolated, but the structure of its well-known extremely shock-sensitive adduct with NH3 has been elucidated — a feat of considerable technical virtuosity.Unlike the volatile, soluble, molecular solid NCI3, the involatile, insoluble compound [Nl3.NH3] has a polymeric structure in which tetrahedral NI4 units are comer-linked into infinite chains of -N-I-N-I- (215 and 230 pm) which in turn are linked into sheets by I-I interactions (336 pm) in the c-direction in addition, one I of each NI4 unit is also loosely attached to an NH3 (253 pm) that projects into the space between the sheets of tetra-hedra. The stmcture resembles that of the linked Si04 units in chain metasilicates (p. 349). A further interesting feature is the presence of linear or almost linear N-I-N groupings which suggest the presence of 3-centre, 4-electron bonds (pp. 63, 64) characteristic of polyhalides and xenon halides (pp. 835-8, 897). [Pg.441]

E.E.C. Directive 80/778/EEC, on the Quality of Running Water Intended for Human Consumption, July 1980. [Pg.739]

Thermocurrent measurements were performed on crystals of RbsNbjOFig and K5Nb3OFi8 along the c direction [440, 443]. Fig. 112 shows the temperature dependences of the pyroelectric coefficients close to room temperature. [Pg.248]

Figure 6-6b. b- anil c-polanzed absorption spectra of T(, single crystal at 4.2 K extended to higher energy. Above 21 U00 cm-1 the b-polarized spectrum shows broad bands which are discussed and assigned in the text (Section 6.4.1), while in c direction the light is completely absorbed. [Pg.408]

Flexural strength (c direction), MPa 80-170 Tensile strength (ab direction), MPa 110 Young s modulus of elasticity, GPa 28-31... [Pg.188]


See other pages where C directed is mentioned: [Pg.646]    [Pg.51]    [Pg.91]    [Pg.4]    [Pg.566]    [Pg.144]    [Pg.521]    [Pg.527]    [Pg.198]    [Pg.313]    [Pg.354]    [Pg.76]    [Pg.551]    [Pg.138]    [Pg.460]    [Pg.27]    [Pg.148]    [Pg.296]    [Pg.269]    [Pg.276]    [Pg.659]    [Pg.336]    [Pg.657]    [Pg.903]    [Pg.1380]    [Pg.496]    [Pg.867]    [Pg.110]    [Pg.407]    [Pg.89]    [Pg.667]    [Pg.314]    [Pg.188]    [Pg.188]    [Pg.271]    [Pg.480]    [Pg.406]   
See also in sourсe #XX -- [ Pg.4 ]




SEARCH



By Direct C-Alkylation

C- Alkylation directed

C-H activation/direct arylation

C-H activation/direct arylation polycondensation

C.I. Direct Red

Direct Arylation by C-H Functionalisation

Direct Boronylation by Transition Metal-catalyzed Aromatic C-H Functionalization

Direct C-H Functionalization of Heteroarenes

Direct C-H alkylation

Direct C-H arylation

Direct C-H couplings

Direct Fluorination of Aliphatics and Non-C-Moieties

Direct Functionalization via C-H Activation of Heterocyclic Substrates

Direct Ring C-H Metallation

Direct arylation of aromatic C-H bonds

Direct conjugate addition via C-H activation nonan-2-one

Direct fluorination of C

Directed C-H borylation

Directed C-H functionalizations

Domino Reactions Involving Heteroatom-Directed C-H Activations

Heteroatom-directed C-H activations

Tether-directed Radical Cyclization Approaches to the Synthesis of C-Glycosides

© 2024 chempedia.info