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Butadiene peroxides

Dimethyl peroxide Diethyl peroxide Di-t-butyl-di-peroxyphthalate Difuroyl peroxide Dibenzoyl peroxide Dimeric ethylidene peroxide Dimeric acetone peroxide Dimeric cyclohexanone peroxide Diozonide of phorone Dimethyl ketone peroxide Ethyl hydroperoxide Ethylene ozonide Hydroxymethyl methyl peroxide Hydroxymethyl hydroperoxide 1-Hydroxyethyl ethyl peroxide 1 -Hydroperoxy-1 -acetoxycyclodecan-6-one Isopropyl percarbonate Isopropyl hydroperoxide Methyl ethyl ketone peroxide Methyl hydroperoxide Methyl ethyl peroxide Monoperoxy succinic acid Nonanoyl peroxide (75% hydrocarbon solution) 1-Naphthoyl peroxide Oxalic acid ester of t-butyl hydroperoxide Ozonide of maleic anhydride Phenylhydrazone hydroperoxide Polymeric butadiene peroxide Polymeric isoprene peroxide Polymeric dimethylbutadiene peroxide Polymeric peroxides of methacrylic acid esters and styrene... [Pg.163]

An explosion and fire occurred in the pipework of a vessel in which dilute butadiene was stored under an inert atmosphere, generated by the combustion of fuel gas in a limited air supply. The inert gas, which contained up to 1.8% of oxygen and traces of oxides of nitrogen, reacted in the vapour phase over an extended period to produce concentrations of gummy material containing up to 64% of butadiene peroxide and 4.2% of a butadiene-nitrogen oxide complex. The deposits eventually decomposed explosively. [Pg.503]

Isoprene (2-Methy 1-1,3-butadiene) Peroxide, Polymeric. (No formula given). Resinous substance decomp slightly above 0°. Reported in Ref 2 as a highly explosive substance. May be prepd by the reaction of isoprene with molecular oxygen... [Pg.400]

The conjugated dienes can be oxidized by air or oxygen and sometimes the reaction may proceed with explosive violence. In cases when no expin takes place, the resulting peroxide may be isolated and examined. In many cases such peroxides proved to be explosive. For example, Butadiene Peroxide explodes with great violence... [Pg.117]

It is not as violent an expl as Butadiene Peroxide described in Vol 2 of Encycl, p B366-R... [Pg.224]

Scott(Ref 2) reported that butadiene heated under pressure undergoes violent thermal decompn and in contact with air or O it may form violently explosive peroxides. Treatment of butadiene with strong NaOH solns(47%) destroys the peroxides. Butadiene peroxide can be detonated by mild heating or mechanical shock. Solid butadiene absorbs enough O at subatmospheric press to make it detonate violently when heated al above its mp(See also 1,3-Butadiene Peroxide Polymer)... [Pg.365]

Poly([7,8-bis(trifluoromethyl)tetracyclo [4.2.0.02 8.05 7]octane-3,4-diyl]-1,2-ethenediyl), 3457 Poly[borane(l)], 0134 crs-Poly (butadiene), 1480 Poly(l,3-butadiene peroxide), 1528 Poly(butadiyne), 1382 Poly(carbon monofluoride), 0336 Poly(chlorotrifluoroethylene), 0589 Poly(l,3-cyclohexadiene peroxide), 2380 Poly(cyclopentadienyltitanium dichloride), 1837 Poly(diazidophosphazene), 4781 Poly(dibromosilylene), 0282 Poly(difluorosilylene), 4324 Poly(dihydroxydioxodisilane), 4474 Poly(dimercuryimmonium acetylide), 0665 Poly(dimercuryimmonium azide), 4606 Poly(dimercuryimmonium bromate), 0253 Poly (dimercury immonium iodide hydrate), 4449 Poly (dimercury immonium perchlorate), 4006 Poly(dimercuryimmonium permanganate), 4603 Poly (dime thylketene peroxide), see Poly(peroxyisobutyrolactone), 1531 Poly(dimethylsiloxane), 0918 Poly(disilicon nitride), 4752 Poly(ethenyl nitrate), see Poly(vinyl nitrate), 0760 Poly(ethylene), 0778 Poly(ethylene terephthalate), 3256 Poly(ethylidene peroxide), 0831 Poly(furan-2,5-diyl), 1398 Poly(germanium dihydride), 4409 Poly(germanium monohydride), 4407 Poly(isobutene), 1578 Poly(methyl methacrylate peroxide), 1913... [Pg.2126]

The storage of the raw materials requires exclusion of air and moisture by inert-gas blanketing. Butadiene peroxides, if formed, are broken down by an aqueous solution of sodium carbonate. A flow diagram for the general process is shown in Figure 2. [Pg.306]

I Methyl methacrylate, 1915 Oxy gen (Gas), Cyclooctatetraene, 4831 Oxygen (Gas). Tetrafluoroethylene, 4831 Poly(l,3-butadiene peroxide). 1533 Poly (1,3-cyclohexadiene peroxide), 2386 Poly (dimetlryIketene peroxide). 1536 Poly (ethylidene peroxide). 0835... [Pg.2455]

See other pages where Butadiene peroxides is mentioned: [Pg.238]    [Pg.687]    [Pg.689]    [Pg.695]    [Pg.238]    [Pg.100]    [Pg.502]    [Pg.519]    [Pg.519]    [Pg.332]    [Pg.223]    [Pg.505]    [Pg.366]    [Pg.366]    [Pg.576]    [Pg.593]    [Pg.594]    [Pg.2546]    [Pg.502]    [Pg.519]    [Pg.519]    [Pg.688]    [Pg.688]    [Pg.696]    [Pg.224]    [Pg.240]    [Pg.502]    [Pg.519]    [Pg.519]    [Pg.2045]    [Pg.171]   
See also in sourсe #XX -- [ Pg.502 ]



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