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Bromine-catalyzed Aziridination of Olefins with Chloramines

1 Bromine-catalyzed Aziridination of Olefins with Chloramines [Pg.455]

In many cases products were isolated as off-white solids after simple recrystalli- [Pg.455]

Despite the effectiveness of chloramine-T in this new method, removal of the toluenesulfonyl group from the newly introduced nitrogen substituent requires harsh conditions. The finding that the N-chloramine salt of tert-butylsulfonamide is also an efficient nitrogen source and the terminal oxidant for aziridination of [Pg.456]




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Aziridination catalyzed

Bromination with bromine

Bromine olefins with

Chloramination

Chloramine

Chloramine Chloramines

Chloramine, with

Of aziridines

Olefin aziridination

Olefin bromination

Olefination catalyzed

Olefins aziridinations

Olefins catalyzed

With Olefins

With aziridines

With bromine

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