Boron tungsten containing

Alloys are metallic substances containing two or more elements which are miscible when molten and do not separate when solidified. They may be liquid or solid. This mixture of elements, usually but not necessarily metals, allows careful manipulation of strength, melting point, corrosion resistance, magnetic, thermal, electrical, and other properties steel, for example, is an alloy of iron and carbon often present with nickel, chromium, copper, aluminium, boron, tungsten, manganese, cobalt, silicon, and other elements. 

Marcantoncetos et al. [112] have described a phosphorimetric method for the determination of traces of boron in seawater. This method is based on the observation that in the glass formed by ethyl ether containing 8% of sulfuric acid at 77 K, boric acid gives luminescent complexes with dibenzoylmethane. A 0.5 ml sample is diluted with 10 ml 96% sulfuric acid, and to 0.05-0.3 ml of this solution 0.1ml 0.04 M dibenzoylmethane in 96% sulfuric acid is added. The solution is diluted to 0.4 ml with 96% sulfuric acid, heated at 70 °C for 1 h, cooled, ethyl ether added in small portions to give a total volume of 5 ml, and the emission measured at 77 K at 508 nm, with excitation at 402 nm. At the level of 22 ng boron per ml, hundredfold excesses of 33 ionic species give errors of less than 10%. However, tungsten and molybdenum both interfere. 

Ferro-alloys Master alloys containing a significant amount of bon and a few elements more or less soluble in molten bon which improve properties of bon and steels. As additives they give bon and steel better characteristics (increased tensile sbength, wear resistance, corrosion resistance, etc.). For master alloy production carbothermic processes are used for large-scale ferro-sihcon, ferro-chromium, ferro-tungsten, ferro-manganese, ferro-nickel and metallothermic processes (mainly alumino and sihco-thermic) for ferro-titanium, ferro-vanadium, ferro-molybdenum, ferro-boron. 

The complex environment of a tokamak does not only contain carbon and tungsten. In devices which apply boronization we find also boron. JET evaporates routinely beryllium in the main chamber leading to a flow of beryllium into the divertor. A similar behaviour we also expect from ITER. Moreover, as in all vacuum devices, there is always some residual oxygen in the machine. For a reliable prediction of erosion and deposition it is necessary to obtain knowledge about sources, transport and deposition of all those species in a fusion device. 

Ignidon on contact with boron-containing materials, iodine, finely divided refractory materials (e.g., asbestos, glass wool, sand, tungsten carbide), fluorinated polymers (with flowing trifluoride). 

Tungsten trioxide, like molybdenum trioxide, possesses in marked degree the property of combining with other acidic oxides, such as phosphorus pentoxide, arsenic pentoxide, silica, and boron trioxide, in varying proportions, producing heteropolyacids which contain the VOL, VII. III. 193 13... 

Tungsten and Nitrogen, Phosphorus, Arsenic, Antimony, and Bismuth—Complex Salts containing Vanadium—Carbides—Complex Cyanogen Derivatives— Compounds with Silicon, Titanium, 2areonium, and Boron. 

The molybdenum catalyst 2 has been used extensively for ADMET polymerization. This complex is easier to handle than the tungsten analog and is more tolerant of functionality. This complex has allowed the synthesis of polymers containing esters, carbonates, ethers, sulfides, aromatic amines, boronates, dichlorosilanes, siloxanes, acetals, and conjugated carbon-carbon double bonds [38-45]. Aldehydes, ketones, and protic functionahty are not tolerated. The molybdenum alkylidene will react with aldehydes and ketones, but not esters, in a Wittig fashion [64]. 

Several studies were published in recent years on electrodeposition of W-Co alloys. Donten and Stojek used pulse electrodeposition to increase the tungsten content in amorphous Co-W alloys. These alloys contained, in addition, small amounts of boron or phosphorous. They showed that, if a symmetrical current pulse was used, the tungsten content in the alloys reached a maximum value of 41.4 at.%, which is higher than in the case of direct current deposition. However, when using any asymmetrical... 

Tungsten resembles molybdenum in showing a remarkable ability to form complex compounds. One molecule of an alkali oxide may be combined with 1, 2, 3, 4, 5, 6, or 8 molecules of WO3 while more complex molecules may contain as much as 5Mr20 condensed with varying amounts of WOa. There are also formed many series of complex tungstates in which W03 combines with varying proportions of the oxides of silicon, phosphorus, arsenic, antimony, vanadium, and boron,... 

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