Bonds dynamics

Sokolov, N. D., Vener, M. V., Savel ev, V. A., 1990, Tentative Study of Strong Hydrogen Bond Dynamics. II. Vibrational Frequency Consideration , J. Mol. Struct. (Theochem), 222, 365. 

Elsaesser TH, Bakker HJ (2002) Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase. Springer, Heidelberg... 

The total Hamiltonian H should include all the vibrational modes involved in the hydrogen bond dynamics, as well as the various couplings taking place between these modes. At last, H would include the relaxation mechanisms. 

Note that Marechal [48,75] proposed an original peeling-off procedure, but in a very different perspective, whose purpose is to eliminate from a given experimental spectrum the features brought by multiple Fermi resonances, thus revealing the intrinsic informations on the hydrogen bond dynamics. 

After raising a selection of topical issues in this field and briefly introducing some spectroscopic and numerical techniques to probe the hydrogen bond dynamics, recent results for alcohol clusters are presented in order of increasing complexity. They are followed by some general conclusions and an outlook on future research goals. 

M. Quack, J. Stohner, and M. A. Suhm, Analytical three body interaction potentials and hydrogen bond dynamics of hydrogen fluoride aggregates (HF)n, n>3.J. Mol. Struct. 599, 381 425 (2001). 

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