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Acetylene, bond angles

Practice working with your Learning By Modeling software Construct molecular models of ethane ethylene and acetylene and compare them with respect to their geometry bond angles and C—H and C—C bond distances... [Pg.56]

One more hybridization scheme is important m organic chemistry It is called sp hybridization and applies when carbon is directly bonded to two atoms as m acetylene The structure of acetylene is shown m Figure 2 18 along with its bond distances and bond angles Its most prominent feature is its linear geometry... [Pg.92]

Figure 8.1 The structure of acetylene, H —C=C—H. The H--0 C bond angles are 180°, and the C=C bond length is 120 pm. The electrostatic potential map shows that the r bonds create a negative (red) belt around the molecule. Figure 8.1 The structure of acetylene, H —C=C—H. The H--0 C bond angles are 180°, and the C=C bond length is 120 pm. The electrostatic potential map shows that the r bonds create a negative (red) belt around the molecule.
To illustrate this rule, consider the ethylene (C2H4) and acetylene (C2H2) molecules. You will recall that the bond angles in these molecules are 120° for ethylene and 180° for acetylene. This implies sp2 hybridization in C2H4 and sp hybridization in C2H2 (see Table 7.4). Using blue lines to represent hybridized electron pairs,... [Pg.188]

The most important alkyne by far is the first member of the series, commonly called acetylene. Recall from Chapter 7 that the C2H2 molecule is linear, with 180° bond angles. The triple bond consists of a sigma bond and two pi bonds each carbon atom is sp-hybridized. The geometries of acetylene and the next member of the series, C3H4, are shown in Figure 22.7. [Pg.587]

Values found for interatomic distances and bond angles in the thirteen hydrocarbons studied are given in Table XIV. The carbon-carbon singlebond distance is found to have the constant value 1.54 = = 0.02 A., being unaffected by the presence of an adjacent double bond or benzene nucleus (provided that it does not form part of a conjugated system). The carbon-carbon double-bond distance in allene and acetylene has the value 1.34 A. This is 0.04 A. less than that formerly given by the table of covalent radii, which has accordingly been revised. The effect of the revision on the bond distance-resonance curve is discussed. [Pg.656]

Arynes present structural features of some interest. They clearly cannot be acetylenic in the usual sense as this would require enormous deformation of the benzene ring in order to accommodate the 180° bond angle required by the sp1 hybridised carbons in an alkyne (p. 9). It seems more likely that the delocalised 7i orbitals of the aromatic system are left largely untouched (aromatic stability thereby being conserved), and that the two available electrons are accommodated in the original sp2 hybrid orbitals (101) ... [Pg.175]

Acetylene (ethyne, C2H2) is linear, i.e. bond angles 180°, and it contains two jt bonds. [Pg.26]

The third observation relates to acetylene (ethyne, C2H2), which is linear, i.e. bond angles of 180°, and contains two it bonds. This introduces what we term triple bonds, actually a combination of one a bond and two n bonds. In this molecule, we invoke another type of hybridization for carbon, that of sp hybrid orbitals. These are a mix of the 2s orbital with one 2p orbital, giving two equivalent sp orbitals. Each hybrid orbital takes one electron, whilst the remaining two electrons are accommodated in two different 2p orbitals (Figure 2.17). [Pg.30]

This makes the acetylene molecule linear, i.e. bond angles of 180°, and there are two n bonds with electron density either side of this axis. The properties of an alkyne, like acetylene, are also special in that the Jt bonds are again much more reactive than the a bond. [Pg.30]

The carbon atoms in acetylene are sp hybridized, with linear (180°) bond angles. The triple bond contains one sigma bond and two perpendicular pi bonds. [Pg.54]

Predict the hybridization, geometry, and bond angles for the carbon atoms in acetylene, C2H2. [Pg.55]

Both the carbon atom and the nitrogen atom of the cyano group are sp hybridized, and the R—C = N bond angle is 180° (linear). The structure of a nitrile is similar to that of a terminal alkyne, except that the nitrogen atom of the nitrile has a lone pair of electrons in place of the acetylenic hydrogen of the alkyne. Figure 21-1 compares the structures of acetonitrile and propyne. [Pg.985]


See other pages where Acetylene, bond angles is mentioned: [Pg.18]    [Pg.262]    [Pg.13]    [Pg.32]    [Pg.212]    [Pg.113]    [Pg.89]    [Pg.92]    [Pg.44]    [Pg.90]    [Pg.3]    [Pg.36]    [Pg.37]    [Pg.37]    [Pg.244]    [Pg.20]    [Pg.27]    [Pg.125]    [Pg.169]    [Pg.247]    [Pg.628]    [Pg.2439]    [Pg.603]    [Pg.180]    [Pg.390]    [Pg.206]    [Pg.214]    [Pg.151]   
See also in sourсe #XX -- [ Pg.365 , Pg.367 ]

See also in sourсe #XX -- [ Pg.365 , Pg.367 ]

See also in sourсe #XX -- [ Pg.365 , Pg.367 ]

See also in sourсe #XX -- [ Pg.341 , Pg.342 , Pg.343 ]

See also in sourсe #XX -- [ Pg.362 , Pg.363 , Pg.364 ]

See also in sourсe #XX -- [ Pg.344 , Pg.347 ]




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Acetylene bonding

Acetylene, bond angles electrostatic potential map

Acetylene, bond angles molecular model

Acetylene, bond angles sp hybrid orbitals

Acetylene, bond angles structure

Bond, acetylenic

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