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BOILING POINTS OF MIXED LIQUIDS

Determination by Dynamical Method.—In determining the boiling points of mixed liquids by the dynamical method, it is of great importance that the vapour phase should be as small as possible, because if a relatively large amount of liquid were converted into vapour the composition of the residual liquid would, as a rule, differ sensibly from that of the original mixture. A reflux condenser must be... [Pg.57]

Comparison of Observed with Calculated Boiling Points. Closely Related Liquids.—We must now consider whether the actual boiling points of mixed liquids agree mth those calculated from the vapour pressures, and, in particular, whether the observed maximum deviations (Pg), agree with those deduced from the vapour pressures (Dj), or, when these are not available, from those calculated... [Pg.63]




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