Beryllium carboxylates basic

Beryllium, bis(trifluoroacetylacetone)-gas chromatography, 1,560 Beryllium acetate basic, 2, 304 complexes, 3, 8 Beryllium borohydride ammine complexes, 3, 8 Beryllium carboxylates basic, 3, 31... 

Be40(02CCH3)e. The acetate is typical of the basic beryllium carboxylates (Be(OH)2 plus ethanoic acid). The structures have O at the centre of a tetrahedron of Be with carb-oxylate spanning each edge of the tetrahedron. Be(02CCH3)2 is formed from BeCl2 and glacial ethanoic acid. 

Basic beryllium acetate, [CAS 543-81-7], Be40(C2lL02)6, is the best known of the beryllium salts of organic adds which can be divided into normal beryllium carboxylates, Be(RCOOh. and beryllium oxide carhoxylates, Re40(RC.00). The basic aceiate is soluble in glacial acetic acid and can readily be crystallized therefrom in very pure form. It is also soluble in chloroform and other organic solvents. It has been used as a source of pure beryllium salts,... 

Beryllium complexes, 3 amines, 7 anionic, 10 hydrates, 6 phthalocyanine, 59 poly carboxylic acid, 33 Schiff bases, 28 Beryllium dichloride ether complexes, 8 Beryllium difluoride ammine complexes, 7 Beryllium dihalides sulfide complexes, 10 Beryllium halides amine complexes, 8 ammonia complexes, 7 carbonyl complexes, 9 Beryllium nitrate basic, 32... 

The above polymers, though soluble when initially prepared, disproportionate at room temperature to basic beryllium carboxylates and a cross-linked polymer. 

Basic beryllium carboxylate, polymers with diacid chlorides, disproportionation of, 243 Benzalazine... 

THE STRUCTURE OF THE CARBOXYL GROUP. II. THE CRYSTAL STRUCTURE OF BASIC BERYLLIUM ACETATE... 

I herc is also an interesting series of basic beryllium complexes with the carboxylic acids which are covalent compounds of remarkable stability. Basic beryllium acetate, Be40(00C.CH3)g melts at 283°, boils at 330° without decomposition and dissolves in CHCI3 as the monomer it lacks ionic properties. Its structure has a central O atom surrounded tetrahedrally by tour... 

The structure of the carboxyl group. II. The crystal structure of basic beryllium acetate. Proc. Natl. Acad. Sci. 20 (1934) 340-345. (Linus Pauling and J. Sherman). SP 52 ... 

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