Benzyl dodecyl ether

Benzyl dodecyl ether (typical procedure). Phenyltellurotrimethylsilane (0.610 g, 2.2 mmol) is added to a solution of benzyl alcohol (0.238 g, 2.2 mmol) in dry benzene (10 mL) under Nj. After stirring for 30 min at room temperature, Znl2 (0.016 g, 0.05 mmol) in benzene (3 mL) is added, followed by dodecanal (0.184 g, 1.0 mmol). Stirring is maintained for 3 h and then HjO is added, the mixture is extracted with benzene and the benzene extract is dried (MgS04) and evaporated under vacuum. The residue is chromatographed on SiOj (elution with benzene/hexane), giving the product (0.265 g (96%)). 

Soon after the introduction of convergent dendrimer synthesis, " hemispherical, aryl-ester-coated, benzyl ether-based dendrons were reported. Attachment to a divalent core and conversion to the polycarboxylate 25 (Fig. 5) yielded dendriiners that facilitated a 200-fold increase in pyrene (26) solubility in water eompared with that of pure water without the dendrimer. Notably, use of sodium dodecyl sulfate (SDS above cmc 9 X 10 M) for pyrene encapsulation resulted in only an 100-fold enhancement. 

Acetic acid, allqfl (C11-C14) esters. See Oxo-dodecyl acetate Acetic acid ammonium sail See Ammonium acetate Acetic acid amyl ester. See Amy I acetate Acetic acid barium salt See Barium acetate Acetic acid ben ester. See Benzyl acetate Acetic acid 2-butoiqf ester. See s-Butyl acetate Acetic acid 2- -butoxyethoxy) ethyl ester. See Diethylene glycol butyl ether acetate... 

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