Benzoyl phenyl carbinol

Synonyms AI3-01680 Benzal alcohol Benzene carbinol Benzene methanol Benzoyl alcohol Benzylicum BRN 0878307 Caswell No. 081F CCRIS 2081 EINECS 202-859-9 EPA pesticide chemical code 009502 Elydroxymethylbenzene a-Elydroxytoluene NC1-C06111 NSC 8044 Phenol carbinol Phenyl carbinol Phenyl methanol Phenyl methyl alcohol a-Toluenol UN 2810. 

Synonyms Benzene carbinol Benzene methanol Benzoyl alcohol Phenyl carbinol Phenyl methanol Hydroxymethyl benzene Hydroxy toluene... 

Synonyms phenyl methanol phenyl carbi-nol benzene carbinol benzoyl alcohol a-hydroxytoluene a-toluenol... 

Phenyl-bis(2-(5-benzoyl)pyrrolyl) methane (215 mg, 0.5 mmol) in 40 mL THF/MeOH (3 1) was reduced by 946 mg NaBH4 (25.0 mmol) to afford the corresponding carbinol, which upon being dried under vacuum for 30 min was immediately subjected to condense with 3.47 mL pyrrole (50 mmol) in the presence of 122 mg Dy(OTf)3 (0.2 mmol) in 200 mL CH2CI2 for 1.3 h at room temperature. After the addition of 0.139 mL triethylamine... 

In certain very limited cases the 750 cm" band shows splitting into a group of weaker bands at the same frequency. This occurs in the cw-forms of phenyl propenyl carbinol and styryl methyl carbinol [37], although the trans forms have only a single band of normal position and intensity. The reasons for this are not known, but it may be connected with steric interferences in the cis-compounds. Benzoyl derivatives also give rise to distortions in this region. The 750 cm" band is not seen in the Raman spectrum and the 690 cm" band appears only weakly. 

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