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Benzo perylene

Common Name Benzo[ / /]perylene Synonym 1,12-benzoperylene, benzoperylene Chemical Name 1,12-benzoperylene CAS Registry No 191-24-2 Molecular Formula C22H12 Molecular Weight 276.330 Melting Point (°C) ... [Pg.823]

Photolytic. The atmospheric half-life was estimated to range from 0.321 to 3.21 h (Atkinson, 1987). Behymer and Hites (1985) determined the effect of different substrates on the rate of photooxidation of benzo[ Ar]perylene using a rotary photoreactor. The photolytic half-lives of benzo[, / ]perylene using silica gel, alumina, and fly ash were 7.0, 22, and 29 h, respectively. [Pg.146]

Benzo[ghi]perylene (1,12-benzoperylene) [191-24-2] M 276,3, m 273°, 277-278.5°, 278-280°, Purified as light green crystals by recrystn from CfiH6 or xylene and sublimes at 320-340° and 0.05mm [UV Helv Chim Acta 42 2315 7959 Chem Ber 65 846 1932 Fluoresc. Spectrum J Chem Soc 3875 7954]. 1,3,5-Trinitrobenzene complex m 310-313° (deep red crystals from C6Hg) picrate m 267-270° (dark red crystals from CgH6) styphnate (2,4,6-trinitroresorcinol complex) m 234° (wine red crystals from CgH6). It recrystallises from propan-l-ol [J Chem Soc 466 7959]. [Pg.123]

BghiP = benzo(g,h,i)perylene CHy = chrysene Per = perylene BbF = benzo-(b)fluoranthene BkF = benzo-(k)fluoranthene BaP = benzo-(a)pyrene IP = indeno-(l,2,3-cd)pyrene Att = anthanthrene. [Pg.39]

Fig. 42 Chromatogram of polycyclic aromatic hydrocarbons on caffeine-impregnated precoated silica gel 60 HPTLC plates with concentrating zone (Merck). The following can be recognized in increasing Rf value. — 1. benzo(ghi)perylene, 2. indeno(l,2,3-cd)pyrene, 3 benzo(a)pyrene, 4. benzo(b)fluoranthene, 5. benzo(k)fluoranthene, 6. fluoranthene. Fig. 42 Chromatogram of polycyclic aromatic hydrocarbons on caffeine-impregnated precoated silica gel 60 HPTLC plates with concentrating zone (Merck). The following can be recognized in increasing Rf value. — 1. benzo(ghi)perylene, 2. indeno(l,2,3-cd)pyrene, 3 benzo(a)pyrene, 4. benzo(b)fluoranthene, 5. benzo(k)fluoranthene, 6. fluoranthene.
Figure 3 depicts profiles of Total PAH fluxes vs. time (36). The following polycyclic hydrocarbons have been determined by high performance liquid chromatography, variable wavelength absorption detection Naphthalene, acenaphthylene, 7,12-dimethylbenzanthracene, 2-methylnaphtalene, fluorene, acenaphtene, phenanthrene, 2,3-dimethylnaphtalene, anthracene, fluoranthene, 1-methylphenanthrene, pyrene, 2,3-benzofluorene, triphenylene, benz(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, perylene, benzo(e)pyrene, 1,2,3,4-dibenzanthracene, benzo(a)pyrene, and 1,2,5,6-dibenzanthracene. [Pg.295]

Benzo(b)fIuoranthrene la 39, 85 Benzo(k)fluoranthrene la 39, 86 Benzo(ghi)perylene la 39,85 Benzophenone derivatives lb 282 Benzo(a)pyrene la 39,85,103 p-Benzoquinone derivatives la 72 Benzothiazoles lb 237 Benzoyl chloride la 70 Benzoylecgonine lb 32,34,35 3,4-Benzpyrene la 60 Benzthiazide lb 188 Benztriazole, 2-(2-hydroxy-5-methyl-phe-nyl)- la 282... [Pg.480]

Benzidine-based dyes Benzo Azurine G Benzo(a)fluoranthene Benzo(b)fluoranthene Benzo(j)fluoranthene Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzopurpurine 4B Benzo(a)pyrene Benzo(c) pyrene Benzo(e) pyrene Benzosulphonazole Benzothiazole Benzoyl peroxide Benzyl chloride Beryllium... [Pg.365]

LutherW, WinT, Vaessen HAMG, van de KampCG, Jekel AA, Jacob J, and Boenke A (1997). The certification of the mass fractions of pyrene, chrysene, benzo[fe]fluoranthene, benzo[o]pyrene, ben-zo[gW]perylene and indeno[i,2,3-cd]pyrene in two coconut oil reference materials (CRM 458 and CRM 459), BCR Information, Reference Materials. Report EUR 17545 EN, 61 pp. [Pg.107]

Figure 5.12 Polyaromatic hydrocarbon species (1) phenanthrene, (2) anthracene, (3) pyrene, (4) benz[o]anthracene, (5) chrysene, (6) naphthacene, (7) benzo[c]phenanthrene, (8) benzo[ghi] fluoranthene, (9) dibenzo[c,g]phenanthrene, (10) benzo[g/ ]perylene, (11) triphenylene, (12) o-terphenyl, (13) m-terphenyl, (14) p-terphenyl, (15) benzo[o]pyrene, (16) tetrabenzonaphthalene, (17) phenanthro[3,4-c]phenanthrene, (18) coronene... Figure 5.12 Polyaromatic hydrocarbon species (1) phenanthrene, (2) anthracene, (3) pyrene, (4) benz[o]anthracene, (5) chrysene, (6) naphthacene, (7) benzo[c]phenanthrene, (8) benzo[ghi] fluoranthene, (9) dibenzo[c,g]phenanthrene, (10) benzo[g/ ]perylene, (11) triphenylene, (12) o-terphenyl, (13) m-terphenyl, (14) p-terphenyl, (15) benzo[o]pyrene, (16) tetrabenzonaphthalene, (17) phenanthro[3,4-c]phenanthrene, (18) coronene...
Reported Henry s law constants of benzo[ghi]perylene at various temperatures ten Hulscher et al. 1992 gas stripping-HPLC/fluo. t/°C H/(Pa m3/mol)... [Pg.825]

Fig. 5 Main contamination sources identified by PCA for sediments, fish, and suface water in the Ebro River basin, and explained variances for each principal component. Variable identification. Organic compounds in sediments 1, summatory of hexachlorocyclohexanes (HCHs) 2, summa-tory of DDTs (DDTs) 3, hexachlorobenzene (HCB) 4, hexachlorobutadiene (HCBu) 5, summatory of trichlorobenzenes (TCBs) 6, naphthalene 7, fluoranthene 8, benzo(a)pyrene 9, benzo(b) fluoranthene 10, benzo(g,h,i)perylene 11, benzo(k)fluoranthene 12, indene(l,2,3-cd)pyrene. Organic compounds in fish 1, hexachlorobenzene (HCB) 2, summatory of hexachlorocyclohexanes (HCHs) 3, o,p-DDD 4, o,p-DDE 5, o,p-DDT 6, p,p-DDD 7, />,/>DDE 8, />,/>DDT 9, summatory of DDTs (DDTs) 10, summatory of trichlorobenzenes (TCBs) 11, hexachlorobutadiene (HCBu) 12, fish length. Physico-chemical parameters in water 1, alkalinity 2, chlorides 3, cyanides 4, total coliforms 5, conductivity at 20°C 6, biological oxygen demand 7, chemical oxygen demand 8, fluorides 9, suspended matter 10, total ammonium 11, nitrates 12, dissolved oxygen 13, phosphates 14, sulfates 15, water temperature 16, air temperature... Fig. 5 Main contamination sources identified by PCA for sediments, fish, and suface water in the Ebro River basin, and explained variances for each principal component. Variable identification. Organic compounds in sediments 1, summatory of hexachlorocyclohexanes (HCHs) 2, summa-tory of DDTs (DDTs) 3, hexachlorobenzene (HCB) 4, hexachlorobutadiene (HCBu) 5, summatory of trichlorobenzenes (TCBs) 6, naphthalene 7, fluoranthene 8, benzo(a)pyrene 9, benzo(b) fluoranthene 10, benzo(g,h,i)perylene 11, benzo(k)fluoranthene 12, indene(l,2,3-cd)pyrene. Organic compounds in fish 1, hexachlorobenzene (HCB) 2, summatory of hexachlorocyclohexanes (HCHs) 3, o,p-DDD 4, o,p-DDE 5, o,p-DDT 6, p,p-DDD 7, />,/>DDE 8, />,/>DDT 9, summatory of DDTs (DDTs) 10, summatory of trichlorobenzenes (TCBs) 11, hexachlorobutadiene (HCBu) 12, fish length. Physico-chemical parameters in water 1, alkalinity 2, chlorides 3, cyanides 4, total coliforms 5, conductivity at 20°C 6, biological oxygen demand 7, chemical oxygen demand 8, fluorides 9, suspended matter 10, total ammonium 11, nitrates 12, dissolved oxygen 13, phosphates 14, sulfates 15, water temperature 16, air temperature...
Finally, three additional individual data matrices were obtained for soil (so1 so2, and so3), in this case with the same number of samples (rows) for each of them. A new soil data matrix (SO) was obtained after individual matrix concatenation containing 36 samples in total (12 samples analyzed in 3 sampling campaigns) (see Fig. 7). Fifteen variables (all of them detected in SE as well) were measured in every sample PAHs (acenaphtylene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(a)pyrene, indeno (l,2,3-cd)pyrene, dibenzo(a,h)anthracene, and benzo(g,h,i)perylene), an organophosphate compound (tributylphosphate), and an OC (4,4 -DDE). [Pg.355]


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