Benzenethiol, 2,4,6-tris

CdSjC Hg, Benzenethiol, 2,4,6-tris(l,l-dimethylethyl)-, cadmium salt, [138306-14-6], 31 22... 

SCjjHj, Benzenethiol, 2,4,6-tris(l,l-dimethylethyl)-, [961-39-7], 31 159 SF303P6ReC 9H48, Rhenium(l+), tris[l,2-ethanediylbis[dimethylphosphine]-PP ]-, (OC-6-11)-, salt with trifluoromethanesulfonic acid (1 1), [ 154419-20-2],... 

Aryl Tellurium Tris[benzenethiolates]/Tris[dithiocarbamates]... 

Dithioalkoxo- and dithiophenoxo-niobium(V) trichlorides [MCl3(SR)2] were obtained from NbCl5 and thiols and benzenethiol respectively.240 The synthesis of tris(benzenedithiolato) complexes was accomplished by reaction of the appropriate metal amide with a mixture of the dithiol and its sodium salt in THF. The structures of (AsPh4)[M(S2C6H4)3]241""243 showed the... 

The reaction of pentachloropyridine (348) with an excess of benzenethiolate ions in l,3-dimethyl-2-imidazolidinone as solvent leads to complete halogen replacement pen-takis(phenylthio)pyridine (349) and l,3,4-tris(phenylthio)[l]benzothieno[3,2-c]pyridine (350) were thus formed (equation 204)345. 

Benzenethiol reacts with trichloromethanesulfenyl chloride to form phenyl tri-chloromethyl disulfide (120), which cyclizes under Friedel-Crafts conditions to 3-chlorobenzo-l,2-dithiolylium chloride (121). Hydrolysis of this affords the dithiolone (77a) (B-66MI43100). 

A similar reaction with benzenethiol produced the aryl tellurium tris[benzenethiolate]4. However, sodium thiosulfonates did not form aryl tellurium tris[thiosulfonates] instead, the aryl tellurium trichloride was reduced to aryl tellurium thiosulfonate. 

Aryl tellurium tris[benzenethiolates] were prepared from aryl tellurium trichlorides and benzenethiol2. 

In a 500-mL. round-bottomed, four-necked glass reactor, fitted with an efllcient mechanical stirrer, thermometer. sintered gas inlet, and a condenser (cooled to — 40 C). was charged the benzenethiol 7 (0.2 mol), finely crushed NaOH (20 g, 0.5 mol). tris[2-(2-methoxyethoxy)ethyl]amine (TDA-I 3.2 g, 0.01 mol), and solvent (TCB or toluene. 200 mL). This mixture was vigorously stirred while chlorodifluoromethane (8) was bubbled through the solution. A noticeable exothermy was observed during the first few min. Then, the medium was heated up to the desired temperature (vide supra) and maintained there for the time indicated, whilst passage ofS was continued. The progress of the reaction was monitored by GC analysis. 

A series of novel 2-amino-6-aryl-9-[2(phosphonomethoxy)ethyl] purine bis (2,2,2-trifluoroethyl) esters (404) has been synthesized by satisfactory regioselec-tive alkylation of 2-amino-6-chloropurine (405) with the bis(tri-fluoroethyl)(2-iodoethoxy)methylphosphonate(406), followed by exchanging the chlorine atom in the resultant intermediate (407) for various substituted and unsubstituted benzenethiols and naphthalenethiols. 6-Phenylthio- and 6-(methoxyphenyl)thio-derivatives showed potent Hepatits B-specific antiviral activity in vitro, and 9[2-(phosphonomethoxy)ethyl] adenine and 9[2-(phosphonomethoxy)ethyl] 2,6-diaminopurine have a broad spectrum of activity against viruses (Scheme 105). ... 

HOyRujCijHio, Ruthenium, nonacarbonyl-(p.3-3,3-dimethyl-l-butynyl)-p,-hydrido-iriangalo-, tri-, 26 329 HO111OS3C11H3, Osmium, decacarbonylhy-dridomethyltri-, 27 206 HO iiOs3SC,eH5, Osmium, (p-benzenethiol-ato)decacarbonyl-p-hydrido-tri-, 26 304 HO11OS3C12H3, Osmium, decacarbonyl-fi.-hydrido(p-methoxymethylidyne)-rria/i-gulo-ui-, 27 202... 

S0ii)0 )Cin, Osmium, p.,-carbonylnonacar-bonyl-pj-thio-tri-, 26 305 SOi[Pg.426]

All operations are carried out under a nitrogen atmosphere using thoroughly degassed solvents. The tetraethylammonium salt of tris(Oethyl dithiocarbonato)-ferrate(II),3 [tris(xanthato)ferrate(II), Fe(etxant)3 ], 3.8 g (6.9 mmole) potassium benzenethiolate, KSC6H5, 4.6 g (31 mmole), and tetraphenylphosphonium chloride, [(C6HS)4P]C1, 5.18 g (13.8 mmole) are added to 25 mL acetonitrile, CH3CN, in a 125-mL Erlenmeyer flask. The suspension is boiled for 15 minutes and the contents of the flask are filtered while hot. 

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