Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Behavior invariant

Long-time behavior ° Invariant manifolds ° Chaos... [Pg.144]

In the same section, we also see that the source of the appropriate analytic behavior of the wave function is outside its defining equation (the Schibdinger equation), and is in general the consequence of either some very basic consideration or of the way that experiments are conducted. The analytic behavior in question can be in the frequency or in the time domain and leads in either case to a Kramers-Kronig type of reciprocal relations. We propose that behind these relations there may be an equation of restriction, but while in the former case (where the variable is the frequency) the equation of resh iction expresses causality (no effect before cause), for the latter case (when the variable is the time), the restriction is in several instances the basic requirement of lower boundedness of energies in (no-relativistic) spectra [39,40]. In a previous work, it has been shown that analyticity plays further roles in these reciprocal relations, in that it ensures that time causality is not violated in the conjugate relations and that (ordinary) gauge invariance is observed [40]. [Pg.97]

The long term behavior of any system (3) is described by so-called invariant measures a probability measure /r is invariant, iff fi f B)) = ft(B) for all measurable subsets B C F. The associated invariant sets are defined by the property that B = f B). Throughout the paper we will restrict our attention to so-called SBR-measures (cf [16]), which are robust with respect to stochastic perturbations. Such measures are the only ones of physical interest. In view of the above considerations about modelling in terms of probabilities, the following interpretation will be crucial given an invariant measure n and a measurable set B C F, the value /r(B) may be understood as the probability of finding the system within B. [Pg.103]

Based on observations concerning the dynamical behavior we already conjectured that there exist seven almost invariant sets - a conjecture that we now want to check numerically. We employ the subdivision algorithm for subtrajectories of length mr = 0.1. The final box-collection corresponding to the total energy E = 4.5 after 18 subdivision steps consists of 18963 boxes. [Pg.112]

Recent mathematical work suggests that—especially for nonlinear phenomena—certain geometric properties can be as important as accuracy and (linear) stability. It has long been known that the flows of Hamiltonian systems posess invariants and symmetries which describe the behavior of groups of nearby trajectories. Consider, for example, a two-dimensional Hamiltonian system such as the planar pendulum H = — cos(g)) or the... [Pg.350]

Note that the conservation of total energy and the conservation of the adiabatic invariants associated to the Born-Oppenheimer limit of the QCMD model provide a simple test for the behavior of a numerical integrator. [Pg.414]

To conclude this section let us note that already, with this very simple model, we find a variety of behaviors. There is a clear effect of the asymmetry of the ions. We have obtained a simple description of the role of the major constituents of the phenomena—coulombic interaction, ideal entropy, and specific interaction. In the Lie group invariant (78) Coulombic attraction leads to the term -cr /2. Ideal entropy yields a contribution proportional to the kinetic pressure 2 g +g ) and the specific part yields a contribution which retains the bilinear form a g +a g g + a g. At high charge densities the asymptotic behavior is determined by the opposition of the coulombic and specific non-coulombic contributions. At low charge densities the entropic contribution is important and, in the case of a totally symmetric electrolyte, the effect of the specific non-coulombic interaction is cancelled so that the behavior of the system is determined by coulombic and entropic contributions. [Pg.835]

Chapter 4 covers much of the same ground as chapter 3 but from a more formal dynamical systems theory approach. The discrete CA world is examined in the context of what is known about the behavior of continuous dynamical systems, and a number of important methodological tools developed by dynamical systems theory (i.e. Lyapunov exponents, invariant measures, and various measures of entropy and... [Pg.18]

Many, possibly all, rules appear to generate asymptotic states which are block-related to configurations evolving according to one of only a small subset of the set of all rules, members of which are left invariant under all block transformations. That is, the infinite time behavior appears to be determined by evolution towards fixed point rule behavior, and the statistical properties of all CA rules can then, in principle, be determined directly from the appropriate block transformations necessary to reach a particular fixed point rule. [Pg.67]

The spatial and temporal dimensions provide a convenient quantitative characterization of the various classes of large time behavior. The homogeneous final states of class cl CA, for example, are characterized by d l = dll = dmeas = dmeas = 0 such states are obviously analogous to limit point attractors in continuous systems. Similarly, the periodic final states of class c2 CA are analogous to limit cycles, although there does not typically exist a unique invariant probability measure on... [Pg.221]

Now, in order for us to recover standard hydrodynamical behavior, we require that the momentum flux density tensor be isotropic i.e. invariant under rotations and reflections. In particular, from the above expansion we see that must be isotropic up to order... [Pg.502]

It is easy to invent rules that conserve particle number, energy, momentum and so on, and to smooth out the apparent lack of structural symmetry (although we have cheated a little in our example of a random walk because the circular symmetry in this case is really a statistical phenomenon and not a reflection of the individual particle motion). The more interesting question is whether relativistically correct (i.e. Lorentz invariant) behavior can also be made to emerge on a Cartesian lattice. Toffoli ([toff89], [toffSOb]) showed that this is possible. [Pg.669]

Mechanical properties of plastics are invariably time-dependent. Rheology of plastics involves plastics in all possible states from the molten state to the glassy or crystalline state (Chapter 6). The rheology of solid plastics within a range of small strains, within the range of linear viscoelasticity, has shown that mechanical behavior has often been successfully related to molecular structure. Studies in this area can have two objectives (1) mechanical characterization of... [Pg.41]

The Franck-Condon model, which decomposes the initial quasistable state of the wave function in terms of free-rotor states and gives the product rotational distribution if no torques are present, was apphed to Ne CI2 and He CI2 and correctly predicted the low / behavior of the distribution, as well as the invariance of the distributions in the Av = 1 and —2 channels [99, 100]. [Pg.408]


See other pages where Behavior invariant is mentioned: [Pg.316]    [Pg.316]    [Pg.108]    [Pg.484]    [Pg.107]    [Pg.230]    [Pg.295]    [Pg.350]    [Pg.498]    [Pg.1]    [Pg.178]    [Pg.515]    [Pg.328]    [Pg.119]    [Pg.69]    [Pg.378]    [Pg.491]    [Pg.96]    [Pg.98]    [Pg.36]    [Pg.100]    [Pg.631]    [Pg.180]    [Pg.108]    [Pg.41]    [Pg.101]    [Pg.286]    [Pg.291]    [Pg.293]    [Pg.478]    [Pg.89]   
See also in sourсe #XX -- [ Pg.455 ]




SEARCH



© 2024 chempedia.info