Barbiturates metal complexes

BAL —see Propan-l-ol, 2,3-dimercapto-Barbiturates metal complexes, 773 Barium... 

An interesting product in the range of azo metal complexes is the nickel complex of azo barbituric acid (34) [6] ... 

Noncovalent interactions in metal complexes of biomolecules may play an important role in the creation of supramolecular structures around the metal center. For instance, extensive three-dimensional hydrogen-bonded stmcmres grow around metal complexes of barbiturates, recognized as the most widely used drugs for the treatment of epilepsy.Electrostatic interactions between a cation and the Trring of an aromatic molecule (cation-tt interactions) are common motifs in protein structures. Little is known about alkali and alkali-earth cation-tt inter-... 

Bacteriochlorins, 851 Barbituric acid metal complexes, 798 Barium alkoxides synthesis, 336 Barium complexes phthalocyanines, 863 porphyrins, 820 Becium homblei copper accumulation, 964 Benzaldehyde, 2-amino-self-condensation aza macrocycles from, 900 Benzamide, o-mercapto-metal complexes, 655 Benzamide oximes metal complexes, 274 Benzamidine, /V, V -diphenyl-metal complexes. 275 Benzene, 1,2-diamino-reactions with dicarbonyl compounds aza macrocycles from, 902 Benzene, 4 methylthionitroso-metal complexes, 804 Benzenedithiolates metal complexes, 605... 

Few attempts have been made to study formation of metal complexes by hallucinogenic drugs, but available data suggest that under physiological conditions there are no strong tendencies. Diazepam (a tranquilizer) binds to metals via nitrogen and forms well-defined complexes MLjXj, M = Cu , or ML3X4, M = Co ", Ni ", X = CP, Br , L = diazepam. Barbiturates form complexes with Co, Ag and Hg ions.2>... 

Barbituric acid, methyl-5-nitroso-zinc complexes, 958 Bayldonite, 960 Benzeneselenic acid metal complexes, 977 Benzimidazole metal complexes, 949 Benzoquinoline zinc complexes, 953 Benzothiazole zinc complexes, 981 Benzotriazole zinc complexes, 950 Benzoxazole metal complexes, 951 Berry twist... 

The crystal-structure determination of bis-(5,5-diethylbarbiturato)bisimi-dazolecobalt(n) is the first of a transition-metal complex in which a drug-active barbiturate is a ligand. Each cobalt atom lies on a crystallographic C2 axis and is surrounded by a tetrahedral arrangement of four nitrogen... 

Beryllium, calcium, boron, and aluminum act in a similar manner. Malonic acid is made from monochloroacetic acid by reaction with potassium cyanide followed by hydrolysis. The acid and the intermediate cyanoacetic acid are used for the synthesis of polymethine dyes, synthetic caffeine, and for the manufacture of diethyl malonate, which is used in the synthesis of barbiturates. Most metals dissolve in aqueous potassium cyanide solutions in the presence of oxygen to form complex cyanides (see Coordination compounds). 

Various mono- and bistriazines have been synthesized by Moral et al. [23] under microwave conditions. The use of a diamine bearing amino groups of different reactivities, selectively gave monotriazines (vii), bistriazines with identical substituents (viii) and differently substituted bistriazines (ix). The newly synthesized bistriazines showed promising applications in supramolecular chemistry based on hydrogen bonds and/or complexation with metals. They are also expected to show interesting fluorescence properties by complexation with cyan-uric and barbituric acid derivatives. 

The synthesis of cahx[4]arene dimelamines with different functionalities and their self-assembly with barbituric and cyanuric acid to hydrogen-bonded nanostructures have been published <05OBC3727> Unique ionophores of penta-crown ethers have been prepared by the reaction of l,3,5-triacryloylhexahydro-l,3,5-triazine (TAHTA) with diaza 18-crown-6 followed by Michael addition, and their binding capabilities towards alkali metal cations studied <05SL2257>. New silver complexes of polydentate ligands including a derivative of pyrazol-l-yl-l,3,5-triazine have been reported <05EJ14370>. 

Trace amounts of cyanide are usually determined by flow injection spectrophotometric procedures. The target species is first halogenated with chlora-mine-T, after which it reacts with a mixture of pyrazolone or barbituric acid and isonicotinic acid or pyridine to form a bluish-violet polymethine dye. The implementation of gas-diffusion modules in the flow setup for hydrogen cyanide separation avoids matrix interferences and enables the adaptation of inherently nonselective detectors, such as metallic silver-wire electrodes for potentiometric measurements. Total inorganic cyanide, including free and complexed species, such as iron-cyanide complexes, may be determined by sample decomposition with UV irradiation and further photometric or amperometric analysis. 

Stoichiometric and kinetic experiments have indicated the likely reaction sequence and mechanisms for the reaction of trans-[Ru NO)-(N02)4(0H)] " with barbituric acid, which gives a violurato complex as product/ Cyclic voltammetry has demonstrated the conversion of [Ru(terpy)(bipy)(NH3)] into [Ru(terpy)(bipy)(N02)] this is oxidation of the ammonia ligand, but is formally classifiable as substitution with respect to the ruthenium(II)/ Stopped-flow cerium(IV) oxidation, flash photolysis, and electrochemical techniques have been used to probe the analogous ligand modification in equation (4). Here, however, the metal... 

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