Azeotropic distillation pinch point curve

The required information about the distillation boundary is obtained from the pinch distillation boundary (PDB) feasibility test [8]. The information is stored in the reachability matrix, as introduced by Rooks et al. [9], which represents the topology of the residue curve map of the mixture. A feasible set of linear independent products has to be selected, where products can be pure components, azeotropes or a chosen product composition. This set is feasible if all products are part of the same distillation region. The singular points of a distillation region usually provide a good set of possible product compositions. The azeotropes are treated as pseudo-components. 

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