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Attempted Observation of High Pressure-Promoted Reversibility in the Cycloadditions

2 Attempted Observation of High Pressure-Promoted Reversibility in the Cycloadditions [Pg.49]

Another appraisal of the mechanism which operates in these repetitive Diels-Alder reactions, was based directly on the isolation of a minor 2 1 adduct 61 alongside the major 2 1 adduct 59 from the reaction of the syn-bisdienophile 38 with the [Pg.49]

4 The Incorporation of [a,c]-Fusion into the Molecular LEGO Set — The Synthesis of Angular Belts and Cages [Pg.50]

The compounds, which have been described in Sections 2 and 3 of this review, have been composed solely of [a,d]-fused six-membered rings. However, as the first part of a research program designed to increase the scope of the repetitive Diels-Alder synthetic methodology, the angular sjw-bisdienophile 74 was identified as a suitable building block to be employed in repetitive Diels-Alder reactions. [Pg.50]




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Cycloaddition reverse

Cycloadditions reversible

In -cycloadditions

Observation of

Observer, The

Of promotion

Pressure reversal

The Observation

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