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Aromatic substituent groups

Ibata was the first to show that the masked carbonyl ylide embedded within the isomiinchnone framework would readily undergo 1,3-dipolar cycloaddition with various dipolarophiles [34], The isolable isomiinchnone 4 was observed to react with dimethyl fumarate to produce cycloadduct 7 which possesses the 7-oxa-2-azabicyclo[2.2.1]heptane skeleton. When the reaction of 1 was carried out using catalytic amounts of Cu(acac)2 in the presence of various dipolarophiles, smooth dipolar cycloaddition was observed to occur giving mixtures of endo and exo isomers. In most cases, the exo isomers were favored. All of Ibata s isomiinchnone cycloadditions contain aromatic substituent groups, presumably selected to facilitate dipole formation. The synthetic utility of the cycloaddition reaction is diminished, however, because of the low reactivity of the aromatic substituents toward further manipulation. [Pg.123]

The electrochemical reversibility of the M(VI)/M(V) couple for the complexes with sterically hindered ligands contrasts with the reported behavior of the [MoO(SPh)4] complex, which exhibited electrochemical irreversibility for the Mo(V)/Mo(VI) step but a reversible Mo(IV)/ Mo(V) couple. The sterically hindered aromatic substituent groups stabilize the molybdenum(VI) complex and decrease relative to the thiophenol derivative. The molybdenum(VI) species can also be isolated by chemical oxidation. [MoO(PFTP)4] was prepared by chemical redu-tion of [MoO(PFTP)4] . The presence of the electron-withdrawing substituents on the aromatic thiolate increases E ei relative to the thio-phenolate derivative. Evidently the properties of these last complexes are influenced primarily by the electron-withdrawing characteristics of the fluorine substituents rather than by steric factors (33). [Pg.422]

Ph = paraffin molecules in heavy fuel oil (>342 °C), Nh = naphthene molecules in heavy fuel oil (>342 "C), Ah = aromatic substituent groups in heavy fuel oil (>342 °C), Cah = aromatic rings in heavy fuel oil (>342 °C), Pl = paraffin molecules in light fuel oil (216-342 °C),... [Pg.310]

The symbol Ar(aryl) is used to stand for any aromatic substituent group in a way analogous to the use of R to mean any alkyl group. For example, aryl halides (ArX) vs. alkyl halides (RX). [Pg.316]

Presumably the greater tendency of an aromatic substituent group to release electrons compared to an alkyl group may account for the increased stability of the formed complex. The Martell group [76] also reported that NJ -dicyclohexylethylene diaminediacetic acid did not form any complex with cupric ion, because the steric-hindrance effect of the dicyclohexyl group interferes with the formation of the structure of chelate rings. [Pg.208]

S Symbol for aromatic substituent groups in the 10-lump model t Catalyst time on stream (s)... [Pg.121]

A halogen atom directly attached to a benzene ring is usually unreactive, unless it is activated by the nature and position of certain other substituent groups. It has been show n by Ullmann, however, that halogen atoms normally of low reactivity will condense with aromatic amines in the presence of an alkali carbonate (to absorb the hydrogen halide formed) and a trace of copper powder or oxide to act as a catalyst. This reaction, known as the Ullmant Condensation, is frequently used to prepare substituted diphenylamines it is exemplified... [Pg.217]

Seemingly the presence of an aromatic substituent in the 4-position of the selenazole ring is necessary for obtaining well-crystallized products compounds with an alkyl group in the 4-position are amorphous and quite difficult to obtain as crystals. [Pg.250]

Low temperature tars contain 30—35 wt % non aromatic hydrocarbons, ca 30% of caustic-extractable phenols in the distillate oils, and 40—50% of aromatic hydrocarbons. The latter usually contain one or more alkyl substituent groups. On atmospheric distillation, coke-oven tars yield 55—60% pitch, whereas CVR tars give 40—50% pitch. The pitch yield from low temperature tars is in the 26—30% range. [Pg.343]

Because nitration has been studied for a wide variety of aromatic compounds, it is a useful reaction with which to illustrate the directing effect of substituent groups. Table 10.3 presents some of the data. A variety of reaction conditions are represented, so direct comparison is not always valid, but the trends are nevertheless clear. It is important to remember that other electrophiles, while following the same qualitative trends, show large quantitative differences in position selectivity. [Pg.562]

The most useful group of aromatic substitutions involving replacement of a substituent group in preference to a hydrogen are electrophilic substitutions of arylsilanes. [Pg.589]

Benzene derivatives. Tbe nomenclature is a combination of the lUPAC system and traditional names. Many of the derivatives are named by the substituent group appearing as the prefbt. These may be considered a subclass of the aliphatic-aromatic hydrocarbon family, which contains both aliphatic and aromatic units in its structures. Thus, alkylbenzenes are made up of a benzene ring and alkane units alkenylbenzenes are Composed of a benzene ring and alkene units and alkynylbenzenes comprise a benzene ring and alkyne units. Examples of alkylbenzenes include... [Pg.310]

You knowr the mechanism of HBr addition to alkenes, and you know the effects of various substituent groups on aromatic substitution. Use this knowledge to predict which of the following two alkenes reacts faster with HBr. Explain your answer by drawing resonance structures of the carbocation intermediates. [Pg.597]

Phenols (ArOH) are relatively acidic, and the presence of a substituent group on the aromatic ring has a large effect. The pKa of unsubstituted phenol, for example, is 9.89, while that of p-nitrophenol is 7.15, Draw resonance structures of the corresponding phenoxide anions and explain the data. [Pg.598]

The substrate scope is limited, as electron-withdrawing groups (X = p-N02 or p-CF3) on the aromatic substituent are not tolerated. However, this route does provide valuable intermediates to unnatural a-amino phosphonic acid analogues and the sulfimine can readily be oxidized to the corresponding sulfonamide, thereby providing an activated aziridine for further manipulation, or it can easily be removed by treatment with a Grignard reagent. [Pg.26]


See other pages where Aromatic substituent groups is mentioned: [Pg.26]    [Pg.26]    [Pg.487]    [Pg.303]    [Pg.310]    [Pg.26]    [Pg.26]    [Pg.237]    [Pg.27]    [Pg.750]    [Pg.83]    [Pg.84]    [Pg.1517]    [Pg.31]    [Pg.312]    [Pg.313]    [Pg.313]    [Pg.26]    [Pg.26]    [Pg.487]    [Pg.303]    [Pg.310]    [Pg.26]    [Pg.26]    [Pg.237]    [Pg.27]    [Pg.750]    [Pg.83]    [Pg.84]    [Pg.1517]    [Pg.31]    [Pg.312]    [Pg.313]    [Pg.313]    [Pg.524]    [Pg.154]    [Pg.159]    [Pg.466]    [Pg.466]    [Pg.151]    [Pg.39]    [Pg.22]    [Pg.55]    [Pg.29]    [Pg.206]    [Pg.218]    [Pg.3]    [Pg.314]    [Pg.216]    [Pg.252]    [Pg.74]    [Pg.29]    [Pg.88]   
See also in sourсe #XX -- [ Pg.312 ]




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Aromatic groups

Aromatic substituent

Aromatic substituents

Groups substituents

Substituent groups

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