Application of small amplitudes the galvanostatic single-pulse method GSP

3 Application of small amplitudes the galvanostatic single-pulse method (GSP) 

In order to measure higher rate constants, shorter electrolysis times should be achievable. To that end, it is better to arrange the experiment in 

If AjF is the faradaic part of the small amplitude current step, we derive from eqn. (18) its relation to Ap = (nF/RT)AE, Ac0 and AcR 

As regards the double layer charging, the first-order expansion of the charge density—potential relationship is 

The rigorous solution of this set of equations has been given by Berzins and Delahay [31] using the method of Laplace transformation. We will 

---