Aniline, synthesis

Henneuse, C. Boxus, T. Tesolin, L. Pantano, G. Marchand-Brynaert, J. One-step hydroxy substitution of 4,4 -dimethoxybenzhydrol with amides, lactams, carbamates, ureas, and anilines. Synthesis 1996, 495-501. 

Thallium compounds, as oxidants 1278, 1281, 1286, 1288, 1311-1325 Thebaine, enzymatic formation of 1216 Thermal analysis 1002 Thermal desorption 938 Thermospray techniques 319 Thiacahx[4]anilines, synthesis of 1416 ThiacaUxarenes,... 

Chloroformamide and iodoformamide compounds, by direct interaction between a palladium carbamoyl complex and CI2 or I2 have been recently reported by us [12b, 13]. As far as the mechanism of catalysis under more drastic temperature conditions is concerned, in which our materials lose rhodium ions, the aniline synthesis could still occur through the above mechanism carried out by Rh " " ions eluted in solution. 

T. Hatano, M. Takeuchi, A. Ikeda, and S. Shinkai, New morphology-controlled poly(aniline) synthesis using anionic porphyrin aggregate as a template, Chem. Lett., 32, 314-315 (2003). 

The above-mentioned two synthetic methods, namely the aniline synthesis and the iodine atom introduction, are new, potentially significant reactions in organic synthetic chemistry that could be applicable to synthesize similar compounds. 

Example benzene to aniline synthesis plan shown in Figure 9.10. 

H. J. Salavagione, D. F. Acevedo, M. C. Miras, A. J. Motheo, C. A. Barbero, Comparative study of 2-amino and 3-aminobenzoic acid copolymerization with aniline synthesis and copolymer properties, /o r a/ of Polymer Science Part A - Polymer Chemistry 2004, 42, 5587. 

Dub, P.A., Rodriguez-Zubiri, M., Daran, J.-C., Brunet, J.-J. and Poll, R., Platinum-catalyzed ethylene hydroamination with aniline Synthesis, characterization, and studies of intermediates, Organometallics 28 (16), 4764-4777 (2009). 

Puterov, Z. KrutoSikov A. Lycka, A. Durcekova, T. (2004). Reactions of Substituted Furan-2-carboxaldehydes and Furo[b]pyrrole Typie Aldehydes with Benzothiazolium Salts. Molecules. Vol. 9, No. 4, pp. 241-255, ISSN. 1420-3049 Riemer, B. Liebscher, J. (1993). Synthesis of Pyrimido[2,l-b]benzoxazolium, Pyrimido[2,l-bjbenzothiazolium and Pyrimido[l,2-a]benzimidazolium Salts by Reaction of 3-Isothiocyanato-2-propeniminium Salts with o-Functionalized Anilines. Synthesis. Vol. 1993, No. 1, pp. 75-76, ISSN. 0039-7881... 

SCHEME 3.45 Aniline synthesis through copper-promoted C-H amination [43]. 

Scheme 1.5 Aniline synthesis from phenyl lithium via nitrogen fixation...

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