Aniline, Azido Derivatives

Azido and Azo Derivatives of N-Methylaniline p-A zido-N-Methy aniline, p-MeNHC6 H4N 3, C7H8N4 mw 148.17, N 37.82% crysts, mp 52° prepd by the action of hydroxylamine hydrochloride on N-methyJ p-nitrosoaniline in aq Na carbonate. Upon exposure to light in thin layers, it turns red, then violet Refs 1) Beil 12, 429 2) A. Angeli ... 

One has to realize that the cycloaddition products, namely the tetrazoles, are in equilibrium with the open chain azido form. The aromatic moiety of the phenol and aniline derivatives not only favors the formation of the cyclic... 

Kirk Othmer II (1966), 864 l-Azido-2-iodobenzene, C6H4N3I mw 245.03, N 17.15% strong smelling oil, bp 90-91° at 0.9 mm Hg, d 1.8893 at 25°, refractive index 1.6631 at 25° prepd by diazotizing aniline with NaN3. No expl props are reported. The l-Azido-3-iodo- and 1-Azido-4-iodo-derivs are also known (Ref 2)... 

Aniline-1,3 -propanediol or 2-Phenylamino-1,3-propanediol, QH5. NH.CH(CH20H)j-not found in Beil. May be considered as the parent comp of derivs listed below. Anilinopropanediol, Azido-, QH,2N40, and Diazido-, CjHnN Oj Derivatives were not found in Beil or CA through 1956... 

Pentryl. See 2-(2 , 4, 6-TrInitro-N-nitranilino Ethanol Nitrate under Aniline ethanol and Derivatives A425-L to A42 )-R Pentryl Homologs A429-R Peracetic Acid, Benzylester. See Acetyl-benzyl peroxide A55-L P hen acyl Azide. See a>-Azido acetophenone under Acetophenone A47-R Phenazone. See Antipyrine A471-R Phenetidine. See Aminophenetole A240-R Phenyl Abietate. See under Abietic Acid A4rL... 

---