Angular-overlap model

Two symmetry parameterizations of the angular overlap model of the ligand field. Relation to the crystal field model. C. E. Schaffer, Struct. Bonding (Berlin), 1973,14, 69-110 (33). 

The functional group in ligand field studies the empirical and theoretical status of the angular overlap model. M. Gerloch and R. G. Woolley, Prog. Inorg. Chem., 1984, 31, 371-446 (87). 

The angular overlap model for the description of the paramagnetic properties of transition metal complexes. A. Benici, C. Benelli and D. Gatteschi, Coord. Chem. Rev., 1984, 60,131 (204). 

Calculations of the Jann-Teller coupling constants for dx systems in octahedral symmetry via the angular overlap model. K. D. Warren, Struct. Bonding (Berlin), 1984, 57,119 (20). 

Crystal field splitting parameter, 2, 309 Crystal field theory, 1, 215-221 angular overlap model, 1, 228 calculations, 1, 220 generality, 1,219 low symmetry, 1,220 /-orbital, 1, 231 Crystal hydrates, 2, 305,306 bond distances, 2, 307 Crystals... 

M. Gerloch, R.G. Woolley, The Functional Group in Ligand-Field Studies The Empirical and Theoretical Status of the Angular Overlap Model , in Prog. 

Schaffer CE (1968) A Perturbation Representation of Weak Covalent Bonding. 5 68-95 Schaffer CE (1973) Two Symmetry Parameterizations of the Angular-Overlap Model of the Ligand-Field. Relation to the Crystal-Field Model. 14 69-110 Scheldt WR, Lee YJ (1987) Recent Advances in the Stereochemistry of Metallotetrapyrroles. 64 1-70... 

Warren KD (1984) Calculations of the Jahn-Teller Coupling Constants for d Systems in Octahedral Symmetry via the Angular Overlap Model. 57 119-145 Warren KD (1977) Ligand Field Theory off-Orbital Sandwich Complexes. 33 97-137 Warren KD (1976) Ligand Field Theory of Metal Sandwich Complexes. 27 45-159 Watson RE, Perlman ML (1975) X-Ray Photoelectron Spectroscopy. Application to Metals and Alloys. 24 83-132... 

Warren, K. D. Calculations of the Jahn-Teller Coupling Constants for d Systems in Octahedral Symmetry via the Angular Overlap Model. Vol. 57, pp. 119-145. 

Schaffer, C.E. Two Symmetry Parameterizations of the Angular-Overlap Model of the Ligand-Field. Relation to the Crystal-Field Model. Vol. 14, pp. 69-110. 

Schaffer CE, Jorgensen CK (1965) The angular overlap model, an attempt to revive the ligand field approaches. Mol Phys 9 401... 

The relative contributions of covalent, electrostatic and other interactions to the CF are not known a priori. The existent models include exclusively either covalent (angular overlap model [42-44] or electrostatic [40, 41, 45] interactions, which seems unjustified.)... 

The term angular overlap model was first used in 1965 to describe a more general treatment, which may also be called the model (12,13). The relative energies of the orbitals in a partly-filled /-shell are expressed in terms of the parameters ex (X = a, rr, etc.), whose coefficients can be calculated from the geometry of the system. The eK model was developed from perturbation theory, but is equivalent to the E2 model when only a-overlap is considered, and to the Yamatera-McClure model for orthoaxial chromophores with linear ligators. The notation ex is often used, where ... 

Five-coordination constitutes an important part of cobalt(II) chemistry both the crystal field and angular overlap models have been used in the analysis of their d—d spectra. Earlier work in this area has been reviewed previously (75). 

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