Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Angular momentum, of atoms

The angular momentum of atoms is quantised and can only take the discrete values... [Pg.4]

Here Jx is the rotor angular momentum and Lx the orbital angular momentum of atom r about the diatom of the r system. The BFx kinetic energy operator is obtained from Eq. (6) by using the fact that J = Lx + Jx is the total angular momentum to eliminate Lx in (6). [Pg.107]

These expressions are known as the Lande g-factors in the context of the total angular momentum of atoms or ions with partially filled electronic shells, which are relevant to the magnetic behavior of insulators. [Pg.554]

The angular momenta of atoms are described by the quantum numbers L, S or J. When spin-orbit coupling is important, it is the total angular momentum J which is a constant of the system. A group of atomic wavefunctions with a common J value - akin to a term, as described in Section 3.6 - comprise (27 -i- 1) members with Mj... [Pg.86]

An example of this kind, in which the energy and angular momentum of the two critical points coincide, occurs for the hydrogen atom in crossed electric and magnetic helds (see Section IVC). The pinched torus then has two pinch points. [Pg.53]

Angular momentum quantum number This quantum number associated with the angular momentum of the electrons in an atom determines the shape of its orbitals. [Pg.117]

It will be shown in Section 9.2.4 that the operator Lz = (ft/i)(d/dp) corresponds to the z component of the angular momentum of the system. That is, for the hydrogen atom it is the vertical component of the angular momentum of the electron. Equation (25) is then equivalent to... [Pg.292]

Following Rutherford s experiments in 1911, Niels Bohr proposed in 1913 a dynamic model of the hydrogen atom that was based on certain assumptions. The first of these assumptions was that there were certain "allowed" orbits in which the electron could move without radiating electromagnetic energy. Further, these were orbits in which the angular momentum of the electron (which for a rotating object is expressed as mvr) is a multiple of h/2ir (which is also written as fi),... [Pg.12]

Orbital angular momentum of an electron in an atom can be measured by the same type of Stern-Gerlach experiment described before for the measurement of electron spin. In this case it will be assumed to use a metal such as magnesium whose atoms have a total electron spin of zero. The magnetic moment... [Pg.232]

Because its base units directly underlie the quantum theory of electrons (i.e., the mass, charge, and angular momentum of the electron itself), the atomic units naturally simplify the fundamental Schrodinger equation for electronic interactions. (Indeed, with the choice me = e = h = 1, the Schrodinger equation reduces to pure numbers, and the solutions of this equation can be determined, once and for all, in a mathematical form that is independent of any subsequent re-measurement of e, me, and h in chosen practical units.) In contrast, textbooks commonly employ the Systeme International d Unites (SI), whose base units were originally chosen without reference to atomic phenomena ... [Pg.723]

Three quantum numbers had been proposed, based on spectral lines and inferences about electron energy levels a principal quantum number to specify energy level of the atom an azimuthal quantum number to specify the angular momentum of electrons moving elliptically and an inner or magnetic quantum number to express the orientation of the plane of the electron s orbit in a magnetic field. 20... [Pg.248]


See other pages where Angular momentum, of atoms is mentioned: [Pg.8]    [Pg.197]    [Pg.8]    [Pg.197]    [Pg.288]    [Pg.4]    [Pg.1553]    [Pg.2006]    [Pg.2048]    [Pg.2077]    [Pg.400]    [Pg.174]    [Pg.237]    [Pg.11]    [Pg.289]    [Pg.23]    [Pg.27]    [Pg.402]    [Pg.960]    [Pg.23]    [Pg.298]    [Pg.45]    [Pg.48]    [Pg.175]    [Pg.195]    [Pg.291]    [Pg.314]    [Pg.432]    [Pg.506]    [Pg.242]    [Pg.263]    [Pg.59]    [Pg.98]    [Pg.100]    [Pg.100]    [Pg.235]    [Pg.342]    [Pg.225]   
See also in sourсe #XX -- [ Pg.237 ]




SEARCH



Angular momentum

Atomic angular momentum

Momentum of atoms

Of momentum

© 2024 chempedia.info