Analysis and development of MEISs

Comparison of MEISs with traditional methods of equilibrium thermodynamics. Initial physico-mathematical assumptions. Physico-mathematical characteristics. Admissible and efficient spheres of application physics, chemistry, engineering systems, biology, and socio-economic systems. [Pg.70]

Classification of MEISs. Models with variable parameters with variable flows and spatially inhomogeneous systems with constraints on the macroscopic kinetics and without them. Specific features of modifications and their comparative capabilities. [Pg.70]

MEISs and macroscopic kinetics. Formalization of constraints on chemical kinetics and transfer processes. Reduction of initial equations determining the limiting rates of processes. Development of the formalization methods of kinetic constraints direct application of kinetics equations, transition from the kinetic to the thermodynamic space, and direct setting of thermodynamic constraints on individual stages of the studied process. Specific features of description of constraints on motion of the ideal and nonideal fluids, heat and mass exchange, transfer of electric charges, radiation, and cross effects. Physicochemical and computational analysis of MEISs with kinetic constraints and the spheres of their effective application. [Pg.70]

Geometrical interpretations of MEISs. Kinetic and thermodynamic surfaces. Representation of kinetics in the space of thermodynamic variables. Thermodynamic tree. Graphs of chemical reactions, hydraulic flows, and electric currents. [Pg.70]