Amorphous static strength

Cycloolefin copolymer (COC) is an amorphous, clear metallocene product of norbomene and ethylene with a spectrum of attractive performance characteristics. Thus, COC (MFI at 190 °C and 2.16 kg = 1.7 dg min, p = 1,020 kg m ) was blended with C2+6 LLDPE (MFI at 190 °C and 2.16 kg = 3.2 dg min , p = 920 kg m ). The mechanical properties of the blends indicate immiscibility, despite the increased LLDPE crystallinity. The presence of COC improved the thermo-oxidative stability. Quasi-static tensile tests showed that increasing fraction of COC in the blends accounts for an enhancement of the elastic modulus and a decrease in the strain at break, while tensile strength passes through a minimum. A significant reduction of the creep compliance of LLDPE could be achieved only for the COC fractions exceeding 20 wt% (Dorigato et al. 2010). 

Lin and coworkers [41] also investigated the static tensile strength and fatigue behavior of long glass-reinforced semicrystalline polyannide and amorphous polycarbonate composites. The static tensile measurement at various tanperatures and tension-tension fatigue loading tests at various levels of stress amplitudes were studied. 

Cohesive strength can be equated with shear resistance and is most frequently assessed by a holding power test, that is, the measurement of the time for a tape to creep a specified distance or to fall from a test panel when a static load is applied in the plane of the backing (see Test Methods). The shear resistance of the amorphous polymer is thus a function of the viscous component of its viscoelastic response to the shear force and can be shown to be related to the steady-state flow viscosity." ... 

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