Molecular glasses, amorphous

Amorphous molecular materials have found successful application as materials for use in OLEDs, constituting a new class of functional organic materials. A new field of organic materials science that deals with amorphous molecular glasses has been opened up. 

Monodisperse analogs of such ir-electron systems, PPV oligomers (molecular glasses) were studied by Bazan and coworkers [217]. The films prepared from 192 by solution casting showed completely amorphous structure due to a tetrahedral structure of the molecule and OLEDs ITO/PVK/192/Al-emitted green light with an efficiency up to 0.22 cd/A (Chart 2.42). 

Figure 3.2. Differential calorimetric curves for the molecular glasses (a) Spiro-sexiphenyl (second heating curve) and (b) Spiro-PBD (first and second heating curve). The glass transition is indicated by a characteristic step, the melting point by an endothermic peak. In (a) recrystallization occurs above Tg, which can be seen by an exothermic peak. The material in (b) forms a stable amorphous glass without recrystallization. The melting point from the first heating curve of a crystalline sample (dotted line) disappears in the second heating cycle (solid line). Only the glass transition is visible.

As stated above, the use of molecular glasses offers the possibility of doping the amorphous films with a variety of dopants that shift the emission energy to longer... 

One final type of laser resonator, which is also applicable for molecular glasses, should be mentioned The random laser, based on coherent backscat-tering in an amplifying medium [212, 213]. In these structures, strongly scattering nanoparticles like Ti02 colloids are randomly dispersed in the amorphous films leading to self-contained optical paths and thus to the localization of optical modes. Since disordered structures are much easier to produce than ordered... 

Thus obtained results show that the polyamorphic transitions occur not only at compression (Si02, H20, etc.) but at extension as well (C) in the systems having stable or metastable crystal analogs with a different density and a different coordination number z. At the minimal z=2 (chain structures) the transitions may occurs only at compression, at the maximal z=12 (close-packed structures) - only at extension, at the intermediate z (2structure-sensitive properties change and new metastable phases can appear. Amorphization under radiation (crystal lattice extension) can be associated with a softening of phonon frequencies. The transitions in the molecular glasses consisted from the molecules with unsaturated bonds are accompanied by creation of atomic or polymeric amorphous systems. 

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