Ammine complexes molybdenum

Until recently, molybdenum(III) ammine complexes have been conspicuous, owing to their scarcity. Previously, the preparation of molybdenum(III)... 

The complexes [PtR(OPh)(dmpe)] (R = Me, Et) have been prepared,566 and the X-ray structure of cis-[PtMe(OR)(PMe3)2].HOR [R = CH(CF3)2] in which the alcohol is H-bonded to the alkoxide ligand, has been determined.567 The transfer of methoxide from [PtMe(OMe)(dppe)] to a cationic molybdenum diene complex has been reported.568 The ammine complexes t/-a/w-[PtMe(NH3)L2]+ (L = phosphine) can be deprotonated to [LPtMe( i.-NH2)]2. which then react with L to form the... 

The catalytic activity of co-ordination compounds in oxidations continues to be examined and, together with the Faraday Society Discussion, other aspects of this area of investigation have been the subject of recent reviews. Redox reactions involving bipyridyl and u-phenanthroline complexes of transition metals have been discussed and catalytic oxidations of complexes of manganese, cobalt, copper, and palladium have also been surveyed. Reviews are also available of ruthenium ammine chemistry, and redox reactions involving molybdenum complexes, together with an account of catalase and peroxidase reactivity of copper(ii) complexes. ... 

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