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Aminosulfenylation

R - CH2 C6H5 Aminosulfenyl-benzylthio-phenyl-essigsdure R = C6H5 Aminosulfenyl-phenyl-phenylthio-... [Pg.394]

Bis(trif1uoramethyl)aminosulfenyl chloride reacts with olefins in the dark at -78 °C to give stereospecifically a/ifr-adducts [76] (equation 12)... [Pg.741]

The Zran.v-stereoselective addition to a C-C double bond is also observed with acyl- and aminosulfenyl chlorides. For example, the reaction of acetylthiosulfenyl chloride with acenaph-thene affords the t/wu-adduct 6 only22. [Pg.534]

Aminosulfenylation of alkenes can also be achieved by trapping the highly reactive (methylthio)-ammonium tetrafluoroborate, formed in situ by alkylation of /V, /V-dimethyImethanesulfenamide with trimethyloxonium tetrafluoroborate42. [Pg.542]

Aminosulfenylation (Addition of Nitrogen, Sulfur) Arylamino-arylthio-addition... [Pg.1185]

Amino-7-oxo-4,5,6,7-tetrahydro- 166 2-(3-Amino-phenoxy)- 971 2-(2-Amino-phenyl)-4,5,6,7-telrahydro- 235 2-(4-Amino-phenylthio)- 972 2-Aminosulfenyl- 868, 997, 998, 999 2-Aminosulfinyl- 997 2-Amino-5-sulfo-... [Pg.1186]

The mechanism of sulfo(IV)diimide formation (75) during the reaction of an aminosulfenyl chloride with trimethylsilyl azide can be depicted by nitrene interception and the subsequent elimination of chlorotrimethylsilane from the adduct. [Pg.134]

Sodium bis(trimethylsilyljamide NyN-Disilyldiaminosulfanes from aminosulfenyl chlorides... [Pg.412]

Aminosulfenyl chlorides from sulfoxylic acid amide esters... [Pg.376]

See other pages where Aminosulfenylation is mentioned: [Pg.1058]    [Pg.1058]    [Pg.252]    [Pg.834]    [Pg.835]    [Pg.493]    [Pg.1154]    [Pg.1185]    [Pg.868]    [Pg.997]    [Pg.999]    [Pg.1007]    [Pg.288]    [Pg.289]    [Pg.493]    [Pg.580]    [Pg.278]    [Pg.301]    [Pg.511]    [Pg.511]    [Pg.262]    [Pg.386]   
See also in sourсe #XX -- [ Pg.1058 ]

See also in sourсe #XX -- [ Pg.834 ]

See also in sourсe #XX -- [ Pg.36 ]



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Aldehydes aminosulfenylation

Aminosulfenyl chlorides

Aminosulfenylation, of alkenes

Aminosulfenylations

Aminosulfenylations alkenes

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