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Aminosulfenyl chlorides

Bis(trif1uoramethyl)aminosulfenyl chloride reacts with olefins in the dark at -78 °C to give stereospecifically a/ifr-adducts [76] (equation 12)... [Pg.741]

The Zran.v-stereoselective addition to a C-C double bond is also observed with acyl- and aminosulfenyl chlorides. For example, the reaction of acetylthiosulfenyl chloride with acenaph-thene affords the t/wu-adduct 6 only22. [Pg.534]

The mechanism of sulfo(IV)diimide formation (75) during the reaction of an aminosulfenyl chloride with trimethylsilyl azide can be depicted by nitrene interception and the subsequent elimination of chlorotrimethylsilane from the adduct. [Pg.134]

Sodium bis(trimethylsilyljamide NyN-Disilyldiaminosulfanes from aminosulfenyl chlorides... [Pg.412]

Aminosulfenyl chlorides from sulfoxylic acid amide esters... [Pg.376]

Aminosugars s. Glycosamines Aminosulfeniom ylids -, reactions, nucleophilic, with - 29, 309 Aminosulfenyl chlorides... [Pg.249]

Without additional reagents S-Aminophosphorothioates from aminosulfenyl chlorides and phosphorous acid esters... [Pg.407]

See other pages where Aminosulfenyl chlorides is mentioned: [Pg.580]    [Pg.278]    [Pg.301]    [Pg.262]    [Pg.573]    [Pg.470]    [Pg.319]    [Pg.481]    [Pg.574]    [Pg.285]    [Pg.250]    [Pg.280]    [Pg.287]    [Pg.241]    [Pg.383]   


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Aminosulfenylation

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