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Aluminum in Organic Synthesis

Main Group Metals in Organic Synthesis. Edited by H. Yamamoto, K. Oshima [Pg.189]

Copyright 2004 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim [Pg.189]

Aluminum is one of the most plentiful metal elements in our planet The list of the most abundant elements by weight in the Earth s layers is headed by oxygen (48.9%), followed by sihcon (26.3%), aluminum (7.7%), iron (4.7%), and calcium (3.4%). Organoaluminum compounds are the cheapest organometalhc compounds. [Pg.190]

Interaction of Aluminum(lll] with Different Functional Croups [Pg.190]

Neutral aluminum(III) species interact with a variety of functional groups. The strong Lewis acidity of aluminum(III) species enables formation of a 1 1 complex by either covalent or coordination bonding - tire former bond is constructed by more reactive anionic species R-M, RO-M or RNH-M (M = metal), and the latter [Pg.190]

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