Aluminum experimental

O Reilly, D. E. (1960). NMR chemical shifts of aluminum experimental data and variational calculation. Journal of Chemical Physics, 32, 1007-12. 

Hansson, G.C. and Goux, C. (1971) Interfadal energies of tilt boundaries in aluminum. Experimental and theoretical determinations. Scripta Metall., 5, 889-894. 

Eurther progress was made in the eighteenth and early nineteenth centuries. Many metals were discovered upon the development of experimental chemistry. The modem metallurgical industry was bom with the invention of steelmaking in 1856 (see Steel). Industrial processes for making zinc (see Zinc and zinc alloys), aluminum (see Aluminumand aluminum alloys), and copper followed before the end of the nineteenth century. These processes made possible the industrial revolution and the development of an industrial society relying heavily on the use of metals. 

Demountable joints are commercially available in great variety in stainless steel, but less so in aluminum alloy or related materials. Experimental joints have been made in which aluminum flanges employ aluminum foil as gasket material. 

Prepa.ra.tlon, There are several methods described in the Hterature using various cobalt catalysts to prepare syndiotactic polybutadiene (29—41). Many of these methods have been experimentally verified others, for example, soluble organoaluminum compounds with cobalt compounds, are difficult to reproduce (30). A cobalt compound coupled with triphenylphosphine aluminum alkyls water complex was reported byJapan Synthetic Rubber Co., Ltd. (fSR) to give a low melting point (T = 75-90° C), low crystallinity (20—30%) syndiotactic polybutadiene (32). This polymer is commercially available. 

C-Alkylation of pyrazoles was a rather uneommon reaction until Grandberg and Kost found the experimental conditions necessary to obtain high yields of 4-benzylpyrazoles (66AHC(6)347). With A-unsubstituted pyrazoles a large excess of aluminum ehloride is neeessary to aeeomplish alkylation at C-4. 

From shock compression of LiF to 13 GPa [68] these results demonstrate that X-ray diffraction can be applied to the study of shock-compressed solids, since diffraction effects can be observed. The fact that diffraction takes place at all implies that crystalline order can exist behind the shock front and the required readjustment to the shocked lattice configuration takes place on a time scale less than 20 ns. Another important experimental result is that the location of (200) reflection implies that the compression is isotropic i.e., shock compression moves atoms closer together in all directions, not just in the direction of shock propoagation. Similar conclusions are reached for shock-compressed single crystals of LiF, aluminum, and graphite [70]. Application of these experimental techniques to pyrolytic BN [71] result in a diffraction pattern (during compression) like that of wurtzite. 

Thus, the combined experimental and theoretical results indicate that the chemical shift observed for the S(2p) core level, of about 1.6 eV, should be due to a secondary effect from the attachment of Al atoms to the adjacent carbon atoms. Indeed, this is fully consistent with tib initio Hartree-Fock ASCF calculations of the chemical shifts in aluminum-oligolhiophene complexes 187], From calculations on a AI2/a-3T complex, where the two AI atoms are attached to the a-car-bons on the central thiophene unit, the chemical shift of the S(2p) level for the central sulfur atom is found to be 1.65 eV, which is in close agreement with the experimental value of about 1.6 eV [84]. It should be pointed out that although several different Al-lhiophene complexes were tested in the ASCF calculations, no stable structure, where an Al atom binds directly to a S atom, was found [87]. 

Morozov and Morozov [32] have also investigated the temperature dependence of the pressure and composition of the vapors and confirmed that the vapors contain aluminum chloride as well as sodium tetra-chloroaluminate. This could be shown experimentally by condensing the vapors which occurred in two zones. In a temperature range from 600 to 800 °C the pressures of A1C13 and NaAlCl4 over sodium tetrachloroaluminate are quite similar they rise from about 10 mm Hg at... 

This expression seemed to correlate the data of Anderson (A5) for non-aluminized propellants, but did not work for aluminized propellants. In later work, Sehgal (S2) has studied the aluminum effect in greater detail. He reports that the effect of aluminum appears to cause incomplete combustion. Price (P10) has reported essentially the same observation. Beckstead derived an expression between the frequency of the oscillations and the L of the combustion chamber. The resulting equations were then shown to correlate experimental data. 

In connection with a discussion of alloys of aluminum and zinc (Pauling, 1949) it was pointed out that an element present in very small quantity in solid solution in another element would have a tendency to assume the valence of the second element. The upper straight line in Fig. 2 is drawn between the value of the lattice constant for pure lead and that calculated for thallium with valence 2-14, equal to that of lead in the state of the pure element. It is seen that it passes through the experimental values of aQ for the alloys with 4-9 and 11-2 atomic percent thallium, thus supporting the suggestion that in these dilute alloys thallium has assumed the same valence as its solvent, lead. 

The possibility of ion formation during the interaction between two Lewis acid molecules as shown in the scheme above is important for the initiation of cationic polymerizations in the absence of cation forming additives (e.g. HX or RX)1). When aluminum-halides A1X3 (X = Cl, Br) are concerned, the ion formation in solution could be experimentally proven163). The formation of ionic species in pure SbCl5/ SbFj system has already been pointed out. 

Nickel, K., Riedel, R., and Petzow, G., Thermodynamic and Experimental Study of High-Purity Aluminum Nitride Formation from Aluminum Chloride by Chemical Vapor Deposition, /. Amer. Ceram. Soc., 72(10) 1804-1810 (1989)... 

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