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Aluminum chloride propylene oxide

Alenylacetylenes, 50,101 Aluminum chloride, with ethylene and p-methoxyphenylacetyl chloride to give 6-methoxy-/3-tetralone, 51,109 with propylene and acetyl chloride to give 4-chloropentan-2-one, 51,116 Amine oxides, anhydrous, 50, 55, 58 Amines, protecting group for, 50,12 AMINES FROM MIXED CARBOXYLIC-CARBONIC ANHYDRIDES 1-PHENYLCYCLOPENTYLAMINE,... [Pg.76]

Synthesis of racemic naproxene Friedel-Crafts acylation (aluminum chloride - nitrobenzene) of p-naphthol methyl ether affords 2-acetyl-6-methoxy naphthalene, which, when treated with either dimethyl sulfonium or dimethylsulfoxonium methylide, gives 2-(6-methoxynaphthalen-2-yl)propylene oxide. Treatment of the latter with boron trifluoride etherate in tetrahydrofuran gives 2-(6-methoxynaphthalen-2-yl)propionaldehyde, which is oxidized using Jones reagent (4 M chromic acid) to yield the racemic 2-(6-methoxynaphthalen-2-yl)propionic acid. [Pg.86]

Alkylation. Friedel-Crafts alkylation (qv) of benzene with ethylene or propylene to produce ethylbenzene [100-41 -4], CgH10, or isopropylbenzene [98-82-8], C9H12 (cumene) is readily accomplished in the liquid or vapor phase with various catalysts such as BF3 (22), aluminum chloride, or supported polyphosphoric acid. The oldest method of alkylation employs the liquid-phase reaction of benzene with anhydrous aluminum chloride and ethylene (23). Ethylbenzene is produced commercially almost entirely for styrene manufacture. Cumene [98-82-8] is catalytically oxidized to cumene hydroperoxide, which is used to manufacture phenol and acetone. Benzene is also alkylated with C1Q—C20 linear alkenes to produce linear alkyl aromatics. Sulfonation of these compounds produces linear alkane sulfonates (LAS) which are used as biodegradable deteigents. [Pg.40]

Cumene or isopropylbenzene, diisopropylbenzene, and secondary butyl-benzene, although produced in smaller quantities than some of the other petrochemical alkylates, are very important petroleum refining products. Cumene is further reacted by oxidation to form cumene hydroperoxide, which is converted to phenol and acetone it is produced by alkylating benzene with propylene catalyzed by either solid or liquid phosphoric acid. Secondary butylbenzene is made by alkylating benzene with normal butylene using the same catalysts. Diisopropylbenzene is made by reacting cumene with propylene over solid phosphoric acid or aluminum chloride catalyst. [Pg.175]

Redox processes involving 178 have also been studied.Anodic oxidation of thianthrene has been eifected in a wide variety of solvents. Use of trifluoracetic acid gives stable solutions of 178 and, if perchloric acid is included, the solid perchlorate salt may be isolated on evaporation of the solvent after electrolysis. Dichloromethane at low temperatures has been used and, at the opposite extreme, fused aluminum chloride-sodium chloride mixtures. " Propylene carbonate permits the ready formation of 178, whereas the inclusion of water in solvent mixtures gives an electrochemical means of sulfoxidizing thianthrene. Reversible oxidation of 178 to thianthrenium dication may be brought about in customary solvents such as nitriles, nitro compounds, and dichloromethane if the solvent is treated with neutral alumina immediately before voltammetry addition of trifluoracetic anhydride to trifluoracetic acid equally ensures a water-free medium. The availability of anhydrous solvent systems which permit the reversible oxidation and reduction of 178 has enabled the determination of the equilibrium constants for the disproportionation of the radical and for its equilibria with other aromatic materials. ... [Pg.103]


See other pages where Aluminum chloride propylene oxide is mentioned: [Pg.549]    [Pg.45]    [Pg.1060]    [Pg.549]    [Pg.40]    [Pg.48]    [Pg.15]    [Pg.149]    [Pg.493]    [Pg.270]    [Pg.185]    [Pg.224]    [Pg.738]    [Pg.947]    [Pg.119]    [Pg.276]    [Pg.124]    [Pg.157]    [Pg.129]    [Pg.245]    [Pg.247]    [Pg.253]    [Pg.260]    [Pg.261]    [Pg.554]    [Pg.555]    [Pg.979]    [Pg.164]    [Pg.172]    [Pg.172]    [Pg.173]    [Pg.272]    [Pg.297]    [Pg.302]    [Pg.307]    [Pg.309]    [Pg.310]    [Pg.313]    [Pg.313]    [Pg.338]   
See also in sourсe #XX -- [ Pg.3 , Pg.769 ]

See also in sourсe #XX -- [ Pg.769 ]

See also in sourсe #XX -- [ Pg.3 , Pg.769 ]




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Aluminum chloride

Aluminum oxidation

Aluminum oxide

Aluminum oxidized

Oxidation chloride

Oxide chlorides

Propylene chloride

Propylene oxide

Propylene oxide oxidation

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