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Alkynes properties

Alkene and alkyne properties Both alkenes and alkynes are nonpolar compounds with relatively low melting and boiling points and low solubilities in water. These properties are similar to those of alkanes. However, alkenes are more reactive than alkanes because double bonds are good sites for chemical reactivity. The triple bonds of alkynes cause them to be generally more reactive than alkenes. [Pg.228]

Colourless liquid with alkenic properties. Many substituted derivatives are known, the preferred method of preparation being the addition of an alkyne to a cyclobutadiene. [Pg.130]

There are no liquid alkynes whieh can be conveniently prepared by the elementary student. Some of the properties of aeetylenie hydrocarbons may be studied with the gas, aeetylene. Although the latter may be prepared in moderate 3deld by the addition of ethylene dibromide to a boiling aleoholic solution of potassium hydroxide or of sodium ethoxide,... [Pg.245]

Another name for aromatic hydrocarbons is arenes Arenes have properties that are much different from alkanes alkenes and alkynes The most important aromatic hydrocarbon... [Pg.58]

The most distinctive aspect of the chemistry of acetylene and terminal alkynes is their acidity As a class compounds of the type RC=CH are the most acidic of all hydro carbons The structural reasons for this property as well as the ways m which it is used to advantage m chemical synthesis are important elements of this chapter... [Pg.363]

Alkynes resemble alkanes and aUcenes m their physical properties They share with these other hydrocarbons the properties of low density and low water solubility They are slightly more polar and generally have slightly higher boiling points than the corre spondmg alkanes and alkenes... [Pg.365]

We have already discussed one important chemical property of alkynes the acidity of acetylene and terminal alkynes In the remaining sections of this chapter several other reactions of alkynes will be explored Most of them will be similar to reactions of alkenes Like alkenes alkynes undergo addition reactions We 11 begin with a reaction familiar to us from our study of alkenes namely catalytic hydrogenation... [Pg.374]

By analogy to the hydration of alkenes hydration of an alkyne is expected to yield an alcohol The kind of alcohol however would be of a special kind one m which the hydroxyl group is a substituent on a carbon-carbon double bond This type of alcohol IS called an enol (the double bond suffix ene plus the alcohol suffix ol) An important property of enols is their rapid isomerization to aldehydes or ketones under the condi tions of their formation... [Pg.379]

The physical properties (boiling point solubility m water dipole moment) of alkynes resemble those of alkanes and alkenes... [Pg.382]

The properties of organometallic compounds are much different from those of the other classes we have studied to this point Most important many organometallic com pounds are powerful sources of nucleophilic carbon something that makes them espe cially valuable to the synthetic organic chemist For example the preparation of alkynes by the reaction of sodium acetylide with alkyl halides (Section 9 6) depends on the presence of a negatively charged nucleophilic carbon m acetylide ion... [Pg.587]

Examples of physical properties of alkynes are given in Appendix 1. [Pg.365]

Physical properties of alkynes [49, p. 251] are essentially similar to those of alkanes and alkenes. These compounds are weakly polar and are insoluble in water, but they are quite soluble in organic solvents of low polarity (e.g., ether, benzene, CCl ). Chemically, alkynes are more reactive than alkanes but behave like alkenes. The triple bond appears to be less reactive than the double bond in some reagents while more reactive in others. In a chemical reaction, the triple bond is usually broken into a double bond, which may eventually split into single bonds. [Pg.308]

As each functional group is discussed in future chapters, the spectroscopic properties of that group will be described. For the present, we ll point out some distinguishing features of the hydrocarbon functional groups already studied and briefly preview some other common functional groups. We should also point out, however, that in addition to interpreting absorptions that ore present in an IR spectrum, it s also possible to get structural information by noticing which absorptions are not present. If the spectrum of a compound has no absorptions at 3300 and 2150 cm-1, the compound is not a terminal alkyne if the spectrum has no absorption near 3400 cm -, the compound Is not an alcohol and so on. [Pg.426]

Aromatic hydrocarbons, sometimes referred to as arenes, can be considered to be derived from benzene, C6H6. Benzene is a transparent, volatile liquid (bp = 80°C) that was discovered by Michael Faraday in 1825. Its formula, C6H6, suggests a high degree of unsaturadon, yet its properties are quite different from those of alkenes or alkynes. [Pg.588]

The superior donor properties of amino groups over alkoxy substituents causes a higher electron density at the metal centre resulting in an increased M-CO bond strength in aminocarbene complexes. Therefore, the primary decarbo-nylation step requires harsher conditions moreover, the CO insertion generating the ketene intermediate cannot compete successfully with a direct electro-cyclisation of the alkyne insertion product, as shown in Scheme 9 for the formation of indenes. Due to that experience amino(aryl)carbene complexes are prone to undergo cyclopentannulation. If, however, the donor capacity of the aminocarbene ligand is reduced by N-acylation, benzannulation becomes feasible [22]. [Pg.131]

Because the types of carbon-carbon bonds present in the molecule tend to dominate its properties, an aliphatic hydrocarbon is first classified as an alkane, alkene, or alkyne. Then the longest chain of carbon atoms is used to form the root of the name. Other hydrocarbon groups attached to the longest chain are named as side chains. [Pg.851]

While these reports are mainly concerned with an evaluation of the peculiar structure of the iminophosphenium cation, this species also reveals cycloaddition properties. The cation shows a [2-t-l] cycloaddition behaviour towards alkynes [50]. With iminophosphanes and alkylazides the cations react with the formation of four- and five-membered heterocyclic ring systems [51], as shown for example in Scheme 9. [Pg.83]


See other pages where Alkynes properties is mentioned: [Pg.98]    [Pg.98]    [Pg.131]    [Pg.174]    [Pg.365]    [Pg.311]    [Pg.261]    [Pg.264]    [Pg.194]    [Pg.365]    [Pg.781]    [Pg.87]    [Pg.199]    [Pg.30]    [Pg.31]    [Pg.36]    [Pg.38]    [Pg.319]    [Pg.3]    [Pg.1028]    [Pg.279]    [Pg.45]   
See also in sourсe #XX -- [ Pg.161 ]




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