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Scandium alkyls

Otero A, Lara-Sanchez A, Femandez-Baeza J, et al. New achiral and chiral NNE heteroscorpionate ligands. Synthesis of homoleptic lithium complexes as well as halide and alkyl scandium and yttrium complexes. Dalton Trans. 2010 39 930-940. [Pg.246]

Benzyl and allyl alcohols which can generate stabilized caibocations give Friedel-Crafts alkylation products with mild Lewis acid catalysts such as scandium triflate. ... [Pg.583]

Scandium triflate and lanthanide triflates also catalyze alkylation by secondary methane-sulfonates. ... [Pg.583]

The methodology of a Lewis acid dissolved in an ionic liquid has been used for Friedel-Crafts alkylation reactions. Song [85] has reported that scandium(III) tri-flate in [BMIM][PFg] acts as an alkylation catalyst in the reaction between benzene and hex-l-ene (Scheme 5.1-55). [Pg.201]

Scheme 5.1-55 The alkylation of benzene with hex-l-ene, catalyzed by scandium(lll) triflate... Scheme 5.1-55 The alkylation of benzene with hex-l-ene, catalyzed by scandium(lll) triflate...
The acetylacetonates are stable in air and readily soluble in organic solvents. From this standpoint, they have the advantage over the alkyls and other alkoxides, which, with the exception of the iron alkoxides, are not as easily soluble. They can be readily synthesized in the laboratory. Many are used extensively as catalysts and are readily available. They are also used in CVD in the deposition of metals such as iridium, scandium and rhenium and of compounds, such as the yttrium-barium-copper oxide complexes, used as superconductors. 1 1 PI Commercially available acetyl-acetonates are shown in Table 4.2. [Pg.91]

In a systematic study, it was demonstrated that, using a specially designed bulky benzamidinate ligand, it is possible to isolate mono(amidinato) dialkyl complexes over the full size range of the Group 3 and lanthanide metals, i.e., from scandium to lanthanum. The synthetic methods leading to the neutral and cationic bis(alkyls) are summarized in Scheme 56. Figure 18 displays the molecular structures of the cations obtained with Sc, Gd, and La. ... [Pg.229]

The guanidinate-supported titanium imido complex [Me2NC(NPr02l2Ti = NAr (Ar = 2,6-Me2C6H3) (cf. Section IILB.2) was reported to be an effective catalyst for the hydroamination of alkynes. The catalytic activity of bulky amidinato bis(alkyl) complexes of scandium and yttrium (cf. Section III.B.l) in the intramolecular hydroamination/cyclization of 2,2-dimethyl-4-pentenylamine has been investigated and compared to the activity of the corresponding cationic mono(alkyl) derivatives. [Pg.336]

The addition of alkyl nitronate anions to imines in the presence of a Lewis acid proceeds in high yield with up to 10 1 diastereoselection favoring the anti isomer. This reaction is used for the stereoselective synthesis of 1,2-diamines (Eq. 4.121).167 Scandium triflate catalyzes the addition of 1-trimethylsilyl nitropropanoate to imines with a similar selectivity.35... [Pg.109]

Non-chlorinated Lewis acids, such as scandium triflate, were found to be good catalysts for Friedel-Crafts alkylation reactions (167). Although no aromatic hydrocarbon alkylation occurred in CH2CI2, [BMIMJPFg, Sc(OTf)3 catalyzed the alkylation of benzene with high yields of the monoalkylated product. The lower acidity of the ionic liquid led to fewer byproducts and therefore higher yields. The products were separated by simple decantation and the catalyst was reused. [Pg.194]

Much work in the review period has concerned enantioselective substitution in five-membered heterocyclics. The enantioselective alkylation of some pyrroles by unsaturated 2-acylimidazoles catalysed by the bis(oxazolinyl)pyridine-scandium(in) triflate complex (31) has been reported.39 Compound (33) is formed in 98% yield and 94% ee from the 2-acylimidazole (32) and pyrrole at —40 °C. A series of enantiomer- ically pure aziridin-2-ylmethanols has been tested as catalysts in the alkylation of /V-mclhylpyrrolc and (V-methylindole by ,/l-unsalura(cd aldehydes.40 Enantiomeric excesses of up to 75% were observed for the alkylation of /V-mcthylpyrrole by ( >crotonaldehyde using (2.S ,3.S )-3-mclhylazirin-2-yl(diphenyl)methanol TFA salt as catalyst to form (34). [Pg.193]

Enantioselective additions of a,f)-unsaturated 2-acyl imidazoles, catalyzed by bis(oxazolinyl)pyridine-scandium(III)triflate complex, were used for the asymmetric synthesis of 3-substituted indoles. The complex 114 was one of the most promising catalysts. The choice of acetonitrile as the solvent and the use of 4 A molecular sieves were also found to be advantageous. The 2-acyl imidazole residue in the alkylation products of u,(i-unsaturated 2-acyl imidazoles could be transformed into synthetically useful amides, esters, carboxylic acid, ketones, and aldehydes (Scheme 32) [105]. Moreover, the catalyst 114 produced both the intramolecular indole alkylation and the 2-substituted indoles in good yield and enantioselectivity (Scheme 33) [106]. The complex... [Pg.22]

Two notable points from the aforegoing discussion are as follows. (1) By far the majority of the known monohalogenoalkyl compounds are of the group VTII transition elements there are very few early transition metal halogenoalkyl compounds known. (2) Very few monofluoroalkyl metal complexes have been prepared. The lack of early transition metal halogenoalkyl compounds may be in part due to the high electropositivity of these metals, which facilitates a- and / -elimination reactions. Related hydride elimination reactions almost certainly occur more easily for early transition metal alkyl compounds than for later transition metal compounds. In this regard it is particularly noteworthy that one of the only early transition metal haloalkyl compounds mentioned is the fluoroethyl scandium com-... [Pg.283]

Chiral 2-(3-oxoalkyl)pyrroles and 3-(3-oxoalkyl)indoles can also be accessed by reaction in the presence of 10 mol% of chiral bis(oxazoline)/metal complexes in CH2C12 in very high yields and with ee values over 90% <2005JA4154>. Alkylation of pyrrole and of substituted indoles with, -unsaturated acyl phosphonates <2003JA10780> or 2-acyl N-methylimidazoles catalyzed by a chiral bis(oxazolinyl)pyridine (pybox)/scandium(III) triflate complex also exhibits good enantioselectivity over a broad range of substrates <2005JA8942>. [Pg.409]


See other pages where Scandium alkyls is mentioned: [Pg.217]    [Pg.117]    [Pg.217]    [Pg.117]    [Pg.233]    [Pg.241]    [Pg.156]    [Pg.306]    [Pg.104]    [Pg.473]    [Pg.324]    [Pg.266]    [Pg.184]    [Pg.85]    [Pg.131]    [Pg.216]    [Pg.223]    [Pg.242]    [Pg.179]    [Pg.137]    [Pg.138]   
See also in sourсe #XX -- [ Pg.299 , Pg.300 ]




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Alkylations scandium trifluoromethanesulfonate

Scandium alkylation

Scandium alkylation

Scandium complexes alkyl compounds

Scandium triflate in alkylation

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