Alkanes epoxy

Jonasson, A. Savoia, M. Persson, O. Fredenslund, A. Isothermal vapor-liquid equilibrium data for ether + glycol, chloroalkene + glycol, epoxy ether + alkane, epoxy ether + alkene, and epoxy ether + chloroalkane systems J. Chetn. Eng. Data 1994,39, 134-139... 

Substitutive lUPAC nomenclature names epoxides as epoxy derivatives of alkanes According to this system ethylene oxide becomes epoxyethane and propylene oxide becomes 1 2 epoxypropane The prefix epoxy always immediately precedes the alkane ending it is not listed m alphabetical order like other substituents... 

Recall from Section 6 18 that epoxides may be named as epoxy derivatives of alkanes in substitutive lUPAC nomenclature... 

Other immobilization methods are based on chemical and physical binding to soHd supports, eg, polysaccharides, polymers, glass, and other chemically and physically stable materials, which are usually modified with functional groups such as amine, carboxy, epoxy, phenyl, or alkane to enable covalent coupling to amino acid side chains on the enzyme surface. These supports may be macroporous, with pore diameters in the range 30—300 nm, to facihtate accommodation of enzyme within a support particle. Ionic and nonionic adsorption to macroporous supports is a gentle, simple, and often efficient method. Use of powdered enzyme, or enzyme precipitated on inert supports, may be adequate for use in nonaqueous media. Entrapment in polysaccharide/polymer gels is used for both cells and isolated enzymes. 

Epoxides are normally nmned as epoxy derivatives of alkanes or as substituted oxiranes. 

Figure 6. XPS C Is (left) and 0 Is (right) spectra of the interfacial substrate surface of epoxy-amine coating on bare steel following cathodic polarization testing (solid curves). Also shown is an approximate curve resolution for each spectrum components of the C Is spectrum are, from left, alkane, ether, and carbonate principal components of the 0 Is spectrum are, from left, iron oxide, carbonate, ether, ad adsorbed water (29.) or sodium Auger ( ). Reproduced with permission from Ref. 29. Copyright 1981, Pergamon Press.

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