Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Aliphatic amines reactions with hypochlorite

As indicated above (Ohme and Schmitz [38a, p. 339]) primary amines converted into the alkylamides of sulfuric acid can be oxidized with sodium hypochlorite to azo compounds. The reaction appears to proceed by way of an intermediate hydrazine, which is ultimately oxidized [38a], The reaction is suitable for the formation of symmetrically substituted azoalkanes. Highly branched primary aliphatic amines have been oxidized with sodium hypochlorite in an aqueous dioxane medium [77],... [Pg.169]

AMMONIUM SULPHATE (7783-20-2) H8N2O4S Noncombustible solid. Aqueous solution is a strong acid. Violent reaction with fused potassium chlorate potassium nitrite. Reacts with caustics, forming ammonia. Hot material reacts with nitrates, nitrites, chlorates. Incompatible with strong oxidizers sulfuric acid aliphatic amines alkanolamines, amides, organic anhydrides isocyanates, vinyl acetate aUcylene oxides epichlorohydrin. Mixture with sodium hypochlorite forms nitrogen trichloride, an unstable explosive material. Attacks metals in the presence of moisture. [Pg.76]

CHLOROMETHYL OXIRANE (106-89-8) C3H5CIO Highly flammable, polymerizable liquid. Forms explosive mixture with air [explosion limits in air (vol %) 3.8 to 21.0 flash point 69°F/21°C 88°F/31 °C autoignition temp 772 F/411 °C Fire Rating 3]. Reacts violently with water. Contact with elevated temperatures, contamination, strong acids, strong bases, metallic halides, aluminum, aluminum chloride iron(III) chloride and other chlorides of iron or zinc can cause explosive polymerization. Violent reaction with aniline, hypochlorite, isopropylamine, potassium ieri-butoxide (ignition), sulfuric acid. Mixtures with trichloroethylene forms explosive dichloroacetylene. Incompatible with aliphatic amines, alkaline earths, alkali... [Pg.249]

See other pages where Aliphatic amines reactions with hypochlorite is mentioned: [Pg.193]    [Pg.580]    [Pg.193]    [Pg.197]    [Pg.17]    [Pg.33]    [Pg.34]    [Pg.38]    [Pg.71]    [Pg.75]    [Pg.133]    [Pg.148]    [Pg.161]    [Pg.162]    [Pg.163]    [Pg.166]    [Pg.168]    [Pg.169]    [Pg.170]    [Pg.175]    [Pg.184]    [Pg.188]    [Pg.192]    [Pg.195]    [Pg.206]    [Pg.206]    [Pg.207]    [Pg.208]    [Pg.210]    [Pg.214]    [Pg.222]    [Pg.225]    [Pg.234]    [Pg.242]    [Pg.249]    [Pg.256]    [Pg.257]    [Pg.257]    [Pg.257]    [Pg.258]    [Pg.283]    [Pg.303]    [Pg.304]    [Pg.304]    [Pg.305]    [Pg.306]    [Pg.314]   
See also in sourсe #XX -- [ Pg.303 ]



SEARCH



Aliphatic amines

Aliphatics reactions with

Amines aliphatic, reactions with

Reaction with amines

Reaction with hypochlorites

Reactions aliphatic amines

© 2024 chempedia.info