Aldehydes orange

CIC Acetaldehyde, although weak in smell and taste, is an important contributor to juiciness and freshness. Ethyl butyrate and (E)-2-hexenol add the fruity, green note and alpha-pinene, octanal and decanal are responsible for the green peely, aldehydic orange note. 

This is a test for the >C = 0 group. Most aldehydes and ketones readily condense with this reagent giving yello v- or orange-coloured precipitates. 

K. Treat with 2,4-dinitrophenylhydrazine reagent (pp. 263, 334). Yellow or orange-yellow precipitates given by most aldehydes and ketones. 

Many esters occur naturally Those of low molecular weight are fairly volatile and many have pleasing odors Esters often form a significant fraction of the fragrant oil of fruits and flowers The aroma of oranges for example contains 30 different esters along with 10 carboxylic acids 34 alcohols 34 aldehydes and ketones and 36 hydrocarbons... 

Substances containing aldehyde or keto groups yield yellow to orange-yellow chromatogram zones on an almost colorless background [1,11]. Silymarin appears red-blue and silydianine ochre-colored [9]. 

The structure of the complex of (S)-tryptophan-derived oxazaborolidine 4 and methacrolein has been investigated in detail by use of H, B and NMR [6b. The proximity of the coordinated aldehyde and indole subunit in the complex is suggested by the appearance of a bright orange color at 210 K, caused by formation of a charge-transfer complex between the 7t-donor indole ring and the acceptor aldehyde. The intermediate is thought to be as shown in Fig. 1.2, in which the s-cis conformer is the reactive one. 

In all the foregoing cases, the percentage of aldehyde or ketone is so high that the estimation by the above processes can be sufficiently accurately carried out on the original oil. With such oils as lemon, orange, hand-pressed lime, and citron or cedrat, however, the proportion of aldehydes is so small that it is not possible to satisfactorily determine it directly on the oil itself by absorption processes, and a preliminary concentration of the aldehydes in the oils by carefully fractionating out the hydrocarbons in vacuo has therefore been proposed by Burgess and Child who recommend the operation to be carried out as follows —... 

By this process lemon oils are found to contain some 2 5 to 3 per cent, aldehydes, hand-pressed lime oil 8 per cent., citron or cedrat oil 4 per cent., and orange oil 0 75 to 1 per cent, but more recent work has shown that these results are somewhat too low, due probably in part to some of the aldehydes distilling over with the terpenes, and for oils containing only a small percentage of aldehydes, a volumetric method, such as the hydroa lamine process, as modified by A. H. Bennet is much to be preferred, as being both simpler and more rapid to carry out, and also. more accurate. 

Aldehydes 4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald reagent) Aldehydes yield violet chromatogram zones on a whitish-yellow background. Some alcohols form yellow to orange-colored chromatogram zones. [2]... 

Aldehydes and ketones can be located as orange or yellow zones after reaction with 2,4-dinitrophenylhydrazine hydrochloride (200 mg dissolved in 2 ml of aqueous HCl). In some cases, heating to 100°C is necessary. 

DNP-derivatives are yellow, orange or red solids, usejul for characterisation of aldehydes and ketones. 

---