Adsorption vessel

None of the selectively adsorbed components is removed from the adsorption vessel until the countercurrent depressurization (blowdown) step. During this step, the strongly adsorbed species are desorbed and recovered at the adsorption inlet of the bed. The reduction in pressure also reduces the amount of gas in the bed. By extending the blowdown with a vacuum (ie, VSA), the productivity of the cycle can be greatiy increased. 

Fig. 31. Apparatus for the study of oxygen exchange with a circulation system. 1, reaction vessel 2, circulation pump 3, valve box 4, cold traps 5, gas sampling ampoule 6, cold trap 1, mano-metric valves 8 to 12, gas storage bulbs 14, gas burette 16, adsorption vessel 24, oxygen purification system. From ref. 245.

Fig. 3.6. Schematic of the volumetric unit. (A) Gas burette filled with mercury (B) diffusion pump (C) adsorption vessel (D) vessel containing some pure condensed nitrogen (E) capillary differential manometer (F,G) manometer (H) vacuum and pressure chamber [16].

Tubes 200 to 400 mm long and 5 to 10 mm in diameter are generally used as adsorption vessels. The choice of the adsorbent depends on the component to be determined and on the degree of moisture in the air sampled. 

Fig.l Schematic diagram of the FR apparatus 1 Sorbate inlet 2 Valve 3 Electromagnets 4 Moving disc 5 Bellows 6 Rotary and turbo drag pumps 7 Computer with A/D and D/A cards 8 Adsorption vessel with zeolite in glass-wool 9 Vacuum connectors 10 Differential Baratron 11 Signal conditioner 12 Reference pressure side... 

CAVERN cryogenic adsorption vessel enabUng rotor nestling CAW calcium tungstate aluminum sodalite... 

Fig. 9.2-5 Radial flow in an adsorption vessel for huge gas flows...

Pour 10 ml of 1 m sodium hydroxide into the adsorption vessel and connect it to the reflux condenser. Set the air flow speed initially at 30 to 60 1/h and pour 10 ml zinc sulphate/cadmium sulphate solution, 10 ml EDTA solu-... 

The concentrated protein solution was supplied to the adsorption vessel by a central tube situated at the bottom of the vessel, well below the liquid-air interface. After the protein adsorption process was finished, the same tube has been used to introduce the buffer solution in order to rinse the samples. 

If this cleaning chamber were operated at 759TorrV (1 mm Fig), there would be 90 volume % less trichloroethylene in the cleaning chamber, and so the adsorption vessel would be considerable smaller — or the same charge of activated carbon would last considerably longer. 

An adsorption vessel of this size would be considered very small by most suppliers of activated carbon. 

When the activated carbon in the adsorption vessel is "full" of solvent, a control S3istem switches flow of solvent-rich exhaust air (or nitrogen) to the other vessel. Then the... 

Use of the canister as an adsorption vessel without local desorption is a "carbon shuttle." It s simply a method of transporting artivated carbon from a supplier to a customer, and returning it to the supplier after it has adsorbed solvent fumes to the extent possible. Essentially, it is a system for "toll processing" " of the activated carbon, and not the solvent — because an equivalent quantity of solvent-free activated carbon is returned to the customer, but no solvent is recovered or returned to the customer. 

The adsorption vessel (drum or canister) is rated for 15 psig internal pressure and 250°F, and constmcted of carbon steel . ... 

CO2 and a temporarily decrease in the gas temperature can be observed (Fig. 1.18). This is due to the adiabatic expansion of the high pressure C02-gas, released to the adsorption vessel including the sorbent sample and a low pressure C02-atmosphere. In the experiment shown in Figure 1.19 the gas valves were opened more slowly (and carefully) so that no adiabatic cooling of the CO2 occured. 

In calculating the adsorbed masses of nitrogen, the thermal expansion of the storage and of the adsorption vessel at higher temperatures must be taken into account. Also slight changes in the so-called helium-volume of the zeolite depending also on temperature should be considered. 

In order to measure simultaneously the mass and the enthalpy of an adsorbed phase, the adsorption vessel in the volumetric instrument. Fig. 2.1, has to be replaced by a calorimeter vessel. Traditionally this vessel is... 

The sensor gas calorimeter (SGC) basically consists of a classical volumetric gas adsorption device complemented by two gas thermometers (cp. Fig. 2.9). The core of the instrument is an adsorption vessel which is placed within a second vessel, the sensor gas jacket. This jacket vessel is filled with gas at pressure (psc) acting as a sensor via a capillary (1) coimecting the vessel with a difference manometer (P3). Additionally, a reference vessel also filled with the (same) sensor gas at pressure (prg) is placed in the thermostat and cormected via capillary (2) to the manometer (P3). Upon opening the valves (V7, V7A) the pressures (psc, Prg) of the sensor gases in the jacket vessel and the reference vessel are equalized, i. e. we have pso = Prg. Thermal equilibrium at temperature (T ) in the system... 

However, if for any reason the temperature of the sensor gas in the jacket vessel is changed, so will be its pressure (pso)- Hence the gas pressures on both sides of the manometer (P3) will be different. This pressure difference signal (Ap = pso - Pro) can be displayed and/or monitored by a supporting data acquisition system. As the sensor gas pressure (pso = Pro + P) is directly related to the temperature (Tsg) of the sensor gas via its thermal equation of state it provides a direct indication of any change of this temperature. Such a change my be caused by heat flowing from (or to) the adsorption vessel to (or from) the thermostat fluid via the sensor gas. 

The instmment is complemented by a gas reservoir and several solenoid valves for the dozing of the gases coming from the gas reservoirs in order to adjust the sorptive gas pressure (p) inside the adsorption vessel. The capillary (3) connecting the adsorption vessel with valves and the sorptive gas reservoir outside the thermostat has to be chosen carefully diameter and length should be such that the sorptive gas coming from the reservoir assumes the temperature of the thermostat (T ), but also evacuation of the adsorption vessel, which for example is necessary for activation processes of the sorbent material, does not take too long or even becomes practically impossible. 

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