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Additives defined

Beyond the density changes that can be used to control method modifications in SFC, the mobile phase composition can also be adjusted. Typical LC solvents are the first choice, most likely because of their availability, but also because of their compatibility with analytical detectors. The most common mobile phase modifiers, which have been used, are methanol, acetonitrile and tetrahydrofuran (THF). Additives, defined as solutes added to the mobile phase in addition to the modifier to counteract any specific analyte-column interactions, are frequently included also to overcome the low polarity of the carbon dioxide mobile phase. Amines are among the most common additives. [Pg.569]

The first instruments used a single magnetic sector (symbol B) to effect separation of the ions. Later, the introduction of double-focusing instruments having an electrostatic sector or electrostatic analyzer (ESA, symbol E) in addition defined a standard which is still valid. [Pg.131]

The same or different jobs may be defined for the selected data files (use common Job/ use different Jobs) and each of these jobs may be inspected and edited before the processing of the whole series is started by clicking the Execute button. With the use diff. Jobs option enabled and clicking the Define diff. Jobs... button, an additional Define Processing Jobs dialog and edit box is opened containing a list of those data files to be processed. Different job files may be selected, edited and assigned to the individual data files. [Pg.211]

In the updated version, presented here, VolSurf descriptors are enlarged from 72 to 94. The new descriptors include elongation, diffusivity, logP, and the so-called best volumes. Definition of the original VolSurf descriptors is given in [5-7] and in Table 8.1 the novel descriptors are additionally defined in detail below. [Pg.174]

In addition, define/i as the overall removal of the total calcium hardness,/2 as the overall removal of the total magnesium hardness, and/as the overall removal of total hardness. Recall that V is the total volume of water treated and that the... [Pg.504]

Fig. 1 depicts a characteristic time-resolved Cu" emission spectrum of Cu-ZSM-5 with two main bands at 480 and 540 nm with different decay times. It evidences different defined Cu sites. Very low intensity bands at 450 and 605 nm (Fig. 5) have been shown to correspond additional defined Cu site and Cu bonded via Si-OH, resp. (9). The intensity of the band at 605 nm had never exceed 3% of the total spectrum intensity and is neglected in the spectra analysis. A lifetime of 5 s was chosen for the spectra evaluation note the importance of the luminescence lifetime for the spectra monitoring, cf Fig. 1. It is suppossed that the Cu luminescence intensity is proportional to the number of the corresponding Cu sites and the saturation of the luminescence intensity is not expected. Zeolites with the Cu/Al ratio below 0.5 were used for luminescence intensity calibration. The relationship between the Cu content in the zeolite and the intensities of the individual bands at 450, 480 and 540 nm (for Cu-ZSM-5) is... Fig. 1 depicts a characteristic time-resolved Cu" emission spectrum of Cu-ZSM-5 with two main bands at 480 and 540 nm with different decay times. It evidences different defined Cu sites. Very low intensity bands at 450 and 605 nm (Fig. 5) have been shown to correspond additional defined Cu site and Cu bonded via Si-OH, resp. (9). The intensity of the band at 605 nm had never exceed 3% of the total spectrum intensity and is neglected in the spectra analysis. A lifetime of 5 s was chosen for the spectra evaluation note the importance of the luminescence lifetime for the spectra monitoring, cf Fig. 1. It is suppossed that the Cu luminescence intensity is proportional to the number of the corresponding Cu sites and the saturation of the luminescence intensity is not expected. Zeolites with the Cu/Al ratio below 0.5 were used for luminescence intensity calibration. The relationship between the Cu content in the zeolite and the intensities of the individual bands at 450, 480 and 540 nm (for Cu-ZSM-5) is...
Here we will introduce three similarity coefficients that have been widely used for both realvalued (i.e. continuous) and binary (dichotomous) descriptors the Tanimoto coefficient, the Dice coefficient and the Cosine coefficient The formulae used to compute these coefficients are given in Table 12.3, where, for completeness, we have also provided the Euclidean and Hamming expressions that were introduced in Section 9.13. Different expressions are used for real-valued data (where the molecule is represented by a vector containing N real values Xj) and for binary data (where each molecule is represented by N binary values). For binary data, we additionally define a to be the number of bits on in the bitstring for A, b to be the number of bits on in the bitstring for B, and c to be the number of bits that are on in both A and B (calculated using the AND operator). [Pg.676]

For rotating systems it is convenient to introduce an additional defined quantity called the angular momentum. This quantity can also be shown to obey a simple balance equation. [Pg.279]

The limit of quantitation (LOQ) is the lowest concentration that produces a signal 10-fold above background, whereas the limit of detection (LOD) is the lowest concentration that produces a signal threefold above background [75]. The assay sensitivity and achievable concentration limits of additives define a window of clearance, which is the difference (on a log scale) between the highest attainable initial contaminant/impurity concentration and the lowest detectable concentration (LOD) of that additive [12]. This difference is the amount that can be measured and thus the amount that can be claimed to have been removed by the process [12]. [Pg.348]

In addition to the equidistant distribution of the nodal points the Lagrange interpolation polynomial are defined via the wave-function not taking into account its derivative. Hermitian interpolation polynomials are in addition defined by the assumption that value and derivation of the wave-function are correct at the nodal points. Hence we get the following ansatz... [Pg.308]

There are many examples where the role of an additive defines its entry point into the formulation. A wetting agent, not to be confused with a pigment dispersant, should clearly be present at the early stages of pre-mixing. Heat sensitive materials such as some biocides may need to be added after cooling. [Pg.41]

All freshwater monitoring programs must clearly identify the end users needs, with the reporting system efficiently and accurately transmitting the analyzed data. Time frames to submit the data should be established in advance and allow for any unforeseen complications. In addition, defining the type of transmission or presentation appropriate for each end user is paramount. [Pg.5019]

The comments led to vigorous discussion on many of the points. In addition, suggestions were offered for additional defining moments or milestones. They included ... [Pg.299]

C(5) and C(10) are displaced by —0.25 and —0.88 A from the plane of the lactone group. The y-lactone ring, which is rraoj-fused to the cyclohexane ring, adopts a non-planar half-chair conformation, with C(Q and C(7) respectively 0.31 and —0.36 A distant from the plane of the other four atoms. The analysis of isocollybolide, which has additionally defined the structure of the isomeric compound cxrllybolide (74), reveals that in this... [Pg.357]

For conventional use this intuitive concept of a compound is sufficient, and there is no difficulty in extending it to a radical. Provided an electron is additionally defined as one of the set of elementary particles By, ions may also be considered to be independent constituents. [Pg.16]

For fronts in anisotropic media, we can additionally define unit vectors no and tq which represent the normal to the front element and a vector orthogonal to the direction of the local characteristic, respectively. By the definition, we have r no = n tq = 0. The normal propagation velocity Vo is parallel to no while the growth velocity Go, defined for the end element of the front, is directed along the vector to. [Pg.151]


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See also in sourсe #XX -- [ Pg.311 ]

See also in sourсe #XX -- [ Pg.159 ]




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