Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Adam-Gibbs relation

B, 109,15068 (2005). Spatially Heterogeneous Dynamics and the Adam-Gibbs Relation in the Dzugutov Liquid. [Pg.156]

C. Adam-Gibbs Relation Between the Configurational Entropy Sc and Relaxation in Glass-Forming Liquids... [Pg.125]

Substituting Eq. (2.9) in the Adam-Gibbs relation for relaxation time Xad T) yields an expression for the strength parameter [18,41]... [Pg.77]

The Adam-Gibbs relation, namely, log [D(T, p)] versus (75c)-1, was found to be valid at each density [53]. [Pg.95]

Correlation between diffiision and entropy Adam-Gibbs relation 157... [Pg.157]

In liquids, one of the most celebrated equations that connects the microscopic dynamics of molecules with thermodynamics is the Adam-Gibbs relation. This relates the translational diffiisivity of the system to configurational entropy as follows ... [Pg.157]

Figure 10.3. Correlations between diffusion coefficient, configurational entropy, and tetrahedral order parameter (/h). Note that the left side of the y-axis represents the logarithm of diffusivity and the right side of ffie y-axis represents (th). The straight line fitting of the data validates the Adam-Gibbs relation between entropy and the diffusion coefficient, as discussed in the text The dashed line shows the correlation between (th) and configurational entropy. Adapted wifli permission from J. Phys. Chem. B, 114 (2010), 3633. Copyright (2010) American Chemical Society. Figure 10.3. Correlations between diffusion coefficient, configurational entropy, and tetrahedral order parameter (/h). Note that the left side of the y-axis represents the logarithm of diffusivity and the right side of ffie y-axis represents (th). The straight line fitting of the data validates the Adam-Gibbs relation between entropy and the diffusion coefficient, as discussed in the text The dashed line shows the correlation between (th) and configurational entropy. Adapted wifli permission from J. Phys. Chem. B, 114 (2010), 3633. Copyright (2010) American Chemical Society.

See other pages where Adam-Gibbs relation is mentioned: [Pg.135]    [Pg.76]    [Pg.63]    [Pg.158]    [Pg.158]    [Pg.287]    [Pg.291]    [Pg.293]    [Pg.316]   
See also in sourсe #XX -- [ Pg.59 ]

See also in sourсe #XX -- [ Pg.157 , Pg.158 , Pg.293 , Pg.295 ]




SEARCH



ADaM

Adam-Gibbs relaxation time-temperature relation

Configurational entropy Adam-Gibbs relation

Diffusion Adam-Gibbs relation

The Adam-Gibbs relation

© 2024 chempedia.info