Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Activated complex structure

The precise energy dependence of k, is complicated as we have seen, it depends on the activated complex structure, on ef, and on 0. It would also reflect changes in the structure of the molecule, but here the model of the molecule was kept constant and the effect of the first-mentioned three variables was observed. [Pg.21]

Even more extensive calculations were done optimizing both the adsorption and the activated complex structures at the MP2/6-31G level. The results are given in Table 3. The approximate activated complex is given in Figure 20. Note that in this case a full optimization of the transitions slate complex has not been... [Pg.286]

Similar assumptions are made with respect to the activated complex structure in isomerization reactions. [Pg.60]

A similar explanation would obviously be invalid for low pre-exponential factors (log A 11 and lower). Indeed, the formally possible allowance for negative activation entropy would have no sense because the activated complex structure would have to be more rigid than that of the initial molecule which is quite improbable. The occurence of reactions with low pre-exponential factors seems to be due to non-adiabaticity of these reactions (see Section III.9) The transmission coefficient omitted in Eq. (18.1) for non-adiabatic reactions can be much lower than unity. Some non-adiabatic decomposition reactions, mainly of three-atom molecules, have been studied recently over a wide temperature range [489]. [Pg.104]

Interpretation of the rate constant in terms of the transition-state method is less complicated. It is usually possible to choose an activated complex structure such as to reproduce both the absolute value and the temperature dependence of kexp(T). This approach that became traditional in the past 40 years also gives somewhat limited information on the reaction cross section but only under additional assumptions [67]. [Pg.134]

Once the potential energy surface has been calculated either by ab initio methods or by the semiempirical approximations, the remaining calculations of activated complex structure and vibration are straightforward. The procedure is (Johnston, 1966) ... [Pg.157]

Figure 3. Energy diagrams for simple bond fission (left) and complex elimination (right) reactions. The molecular internal energy is plotted as a function of reaction coordinate q, i.e., of a suitable bond length changing markedly during the reaction. The zero-point energies of the reactant, product, and intermediate activated complex structures are denoted by E p, and respectively. AHl and Eq are the enthalpy of reaction at 0 K and the critical energy for dissociation. Figure 3. Energy diagrams for simple bond fission (left) and complex elimination (right) reactions. The molecular internal energy is plotted as a function of reaction coordinate q, i.e., of a suitable bond length changing markedly during the reaction. The zero-point energies of the reactant, product, and intermediate activated complex structures are denoted by E p, and respectively. AHl and Eq are the enthalpy of reaction at 0 K and the critical energy for dissociation.
The theory of unimoiecular dissociation and recombination reactions described here provides a compact format for analysis and extrapolation of experimental data as well as for estimation of unknown unimoiecular rate coefficients. It has been applied in practice to some selected reactions and should find wider use in the future. The quality of the analysis depends on the availability of experimental data at least for a limited range of conditions. By the use of these experiments, uncertain theoretical parameters can be fitted and a full set of [M]- and T-dependent rate coefficients constructed. If no such experimental data are available, the quality of ab initio predictions will depend primarily on the accuracy of the thermochemical parameters AH and on estimates of weak collision efficiencies and of activated complex structural parameters. [Pg.195]

The structure that exists at the transition state is some times referred to as the tran sition structure or the activated complex... [Pg.108]

Scheffzek, K., et al. The Ras-RasGAP complex structural basis for GTPase activation and its loss in oncogenic Ras mutants. Science 277 333-338, 1997. [Pg.281]

These examples illustrate the relationship between kinetic results and the determination of reaction mechanism. Kinetic results can exclude from consideration all mechanisms that require a rate law different from the observed one. It is often true, however, that related mechanisms give rise to identical predicted rate expressions. In this case, the mechanisms are kinetically equivalent, and a choice between them is not possible on the basis of kinetic data. A further limitation on the information that kinetic studies provide should also be recognized. Although the data can give the composition of the activated complex for the rate-determining step and preceding steps, it provides no information about the structure of the intermediate. Sometimes the structure can be inferred from related chemical experience, but it is never established by kinetic data alone. [Pg.199]

More complex structures, such as 19, exhibit similar activation energies. Compound 19 has also been used to demonstrate that the stereochemistry is antarafacial, as predicted. ... [Pg.625]

The extent to which B3O3 rings catenate into more complex structures or hydrolyse into smaller units such as [B(OH)4] clearly depends sensitively on the activity (concentration) of water in the system, on the stoichiometric ratio of metal ions to boron and on the temperature (7-A5). [Pg.206]

At the same time proof accumulated that arynes can be considered as real intermediates and not, e.g., as resonance structures in the activation complex of the transition state ... [Pg.124]

Stable heterocyclic compounds having the intermediate-complex structure are well known. Where these compounds result from addition of a strongly nucleophilic anion to an A-alkylazinium cation or to a very activated substrate or must pass through a high-energy second... [Pg.170]

Finally, there is active interest in developing catalyst systems, both ballistic and polymerization, that would promote combustion stability at high pressures (especially in metal-free systems for smokeless applications) and allow processing lattitude for relatively large motors. The ferric-based systems currently being used fall short of these performance measures. Compounds that form complex structures with the metal chelate to reduce its activity to acceptable levels seem to be most promising. Interestingly, the use of an antibiotic has been cited in this context [19],... [Pg.707]

The transition state represents the highcsl-energy structure involved in this step of the reaction. It is unstable and can t be isolated, but we can nevertheless imagine it to be an activated complex of the two reactants in which both the C=C tt bond and H-Br bond are partially broken and the new C-H bond is partially formed (Figure 5.5). [Pg.158]

Death domain (DD) superfamily consists of structurally related homotypic interaction motifs of approximately 90 amino acids. The motifs are organized in six antiparallel amphipathic a-helices, the so-called DD fold. The four members of the super family are the death domain (DD), the death effector domain (DED), the caspase activation and recruitment domain (CARD), and the Pyrin domain. All are important mediators for the assembly of caspase activating complexes. [Pg.419]

As we will see below, this original and complex structure of the mGlu receptors offers multiple possibilities to develop dtugs modulating their activity. [Pg.761]

To explain the observed magnitude of E and other kinetic features of reaction, a homogeneous bimolecular interaction between neighbouring CIO4 ions in the crystal structure was postulated and application of the activated complex theory to this model gave good agreement with the experimental observations. [Pg.186]


See other pages where Activated complex structure is mentioned: [Pg.105]    [Pg.13]    [Pg.192]    [Pg.411]    [Pg.112]    [Pg.3]    [Pg.105]    [Pg.13]    [Pg.192]    [Pg.411]    [Pg.112]    [Pg.3]    [Pg.28]    [Pg.285]    [Pg.35]    [Pg.97]    [Pg.855]    [Pg.855]    [Pg.2438]    [Pg.58]    [Pg.364]    [Pg.107]    [Pg.238]    [Pg.481]    [Pg.4]    [Pg.71]    [Pg.320]    [Pg.251]    [Pg.259]    [Pg.4]    [Pg.91]    [Pg.452]    [Pg.198]    [Pg.93]   
See also in sourсe #XX -- [ Pg.91 ]

See also in sourсe #XX -- [ Pg.2 , Pg.283 , Pg.284 ]




SEARCH



Activated complex structure estimation

Activated complexes, energy levels structure

Lifetime, active complex transition structure

Platinum-amine complexes structure-activity relationships

Structural complexity, active sites

Structural complexity, active sites reaction free energy

Structure active ternary complex

Structure, Bonding, and Activation of Dihydrogen Complexes

Zeolite catalysis structural complexity, active sites

© 2024 chempedia.info