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Clouds actinic flux effects

All the calculated actinic fluxes discussed so far refer to a cloudless sky. The effects of clouds are... [Pg.72]

The net enhancement factor for a droplet consisting of pure water can be as much as 1.6 (Madronich, 1987). Calculations by Ruggaber et al. (1997) suggest that the actinic flux inside cloud drops with a typical size distribution and dissolved particulate matter is more than a factor of two greater than in the cloud interstitial air. This effect of enhanced actinic flux inside droplets may be quite important for aqueous-phase photochemistry in fogs and clouds. [Pg.75]

Madronich, S. Photodissodation in the atmosphere 1. Actinic flux and the effects of ground reflections and clouds. J. Geophys. Res. 92 (1987) 9740-9752. [Pg.294]

In the calculation for atmospheric photodissociation reactions, how to calculate the effective solar intensity is a major issue, because not only direct irradiation from the sun, but light from all directions reflected and scattered by the ground surface, clouds, atmospheric molecules, and aerosols can contribute to photolysis. Furthermore, in the troposphere for example, only solar radiation that has not been absorbed by atmospheric molecules in the higher atmosphere, the stratosphere and above, can cause photolytic reactions. The spherically integrated solar intensity after considering those many atmospheric processes is called the actinic flux F (X) (photons cm s ), which means solar irradiation valid for photochemical effect. In atmospheric chemistry, jp is often used instead of kp for representing photolysis rate constant. Photodissociation rate constant in the atmosphere can be expressed using these parameters as... [Pg.20]


See other pages where Clouds actinic flux effects is mentioned: [Pg.297]    [Pg.57]    [Pg.85]    [Pg.690]    [Pg.53]    [Pg.804]    [Pg.29]   
See also in sourсe #XX -- [ Pg.72 , Pg.73 , Pg.74 ]




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