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Acids peroxyformic acid

Performic Acid. (Peroxyformic Acid, Permetha-noic Acid, Formylhydroperoxide). ACOOOH, mw 62.03, the 90% soln is a colorl liq, is prone to expld on contact with metals, their oxides, reducing substances, or on distn. A 90% soln is obtained when a mixt of 20g formic acid, 25g 100% hydrogen peroxide and 6.5g sulfuric acid is ailowed to interact for 2 hrs and is then distd. Misc with w, ale, eth sol in benz and chlf (Refs 6 8)... [Pg.659]

TABLE 2. Comparison of the calculated barriers (kcal mol-1) for the oxidation of alkenes, dimethyl sulfide, trimethylamine and trimethylphosphine with peroxynitrous acid, peroxyformic acid and dimethyldioxirane (DMDO)... [Pg.7]

Ede RM, Brunow G (1989) Formic acid/peroxyformic acid pulping II Synthesis of 3 aryl 2,3 dihydro 7 methoxy-2-benzofuranmethanols - model compounds for lignin acidolysis products Holzforschung 43 127-129... [Pg.298]

The reaction of alkenes with peroxy acids provides for convenient and selective oxidation of double bonds. The peroxy acids most commonly used in the laboratory are m-chloroperoxybenzoic acid (mCPBA), monoperoxyphthalic acid magnesium salt (MMPP), peroxybenzoic acid, peroxyformic acid, peroxyacetic acid, trifluoroper-oxyacetic acid, and 7-butyl hydroperoxide f(CH3)3COOH]. The order of reactivity for... [Pg.160]

TELLURIUM (13494-80-9) Finely divided powder or dust may be flammable and explosive. Violent reaction with strong oxidizers, bromine pentafluoride, halogens, interhalogens, iodine pentafluoride, hexalithium disilicide, lithium silicide, nitrosyl fluoride, oxygen difluoride, sodium peroxide, sulfur, zinc. Incompatible with cadmium, cesium, hafnium, strong bases, chemically active metals, iodic acid, iodine oxide, lead chlorite, lead oxide, mercury oxides, nitric acid, peroxyformic acid, platinum, silver bromate/iodate/ fluoride, nitryl fluoride, sodium nitrate. [Pg.1121]

Formaldehyde forms explosive mixtures with air in the range 7-73% by volume. It explodes when heated with NO2 at 180°C (356°F), bums with explosive violence when treated with a mixture of perchloric acid and aniline, and explodes with concentrated performic acid (peroxyformic acid),... [Pg.167]

See other pages where Acids peroxyformic acid is mentioned: [Pg.15]    [Pg.78]    [Pg.15]    [Pg.78]    [Pg.435]    [Pg.827]    [Pg.1233]    [Pg.959]    [Pg.629]    [Pg.631]    [Pg.631]    [Pg.632]    [Pg.653]    [Pg.759]    [Pg.939]    [Pg.847]    [Pg.848]    [Pg.848]    [Pg.849]    [Pg.851]    [Pg.851]    [Pg.1048]    [Pg.1048]   
See also in sourсe #XX -- [ Pg.128 ]



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